Application of nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, UV–Visible spectroscopy and kinetic modeling for elucidation of adsorption chemistry in uptake of tetracycline by zeolite beta
作者： Jin Kang , Huijuan Liu , Yu-Ming Zheng , Jiuhui Qu , J. Paul Chen
DOI: 10.1016/J.JCIS.2010.10.065
关键词:
摘要: Abstract Extensive usage of tetracycline has resulted in its contamination surface water and groundwater. The adsorption on zeolite beta was systematically investigated for the decontamination antibiotic polluted this study. Ninety percent uptake by occured 0.25 h, equilibrium obtained within 3 h, which well described an intraparticle diffusion model. generally increased when pH from 4.0 to 5.0, then decreased significantly as further increased, caused pH-dependent speciation charge beta. Both Freundlich Langmuir equations isotherm. A thermodynamic analysis showed that sorption process spontaneous endothermic. Aluminum atoms played a crucial role uptake; with increasing aluminum content zeolite. UV–Visible spectroscopy study spectra changed upon interaction beta, could be ascribed formation complexes surface. Nuclear magnetic resonance confirmed participation Al adsorption. Fourier transform infrared studies amino functional groups were involved complexation
core.ac.uk
harvard.edu
elsevier.com
sci-hub.se 参考文章(27)
Chi Tien, Adsorption calculations and modeling ,(1994)
Linh T. Chiem, Le Huynh, John Ralston, David A. Beattie, An in situ ATR-FTIR study of polyacrylamide adsorption at the talc surface. Journal of Colloid and Interface Science. ,vol. 297, pp. 54- 61 ,(2006) , 10.1016/J.JCIS.2005.10.037
Carlos F. Linares, María Brikgi, Interaction between antimicrobial drugs and antacid based on cancrinite-type zeolite Microporous and Mesoporous Materials. ,vol. 96, pp. 141- 148 ,(2006) , 10.1016/J.MICROMESO.2006.05.038
Jutta R. V. Pils, David A. Laird, Sorption of tetracycline and chlortetracycline on K- and Ca-saturated soil clays, humic substances, and clay-humic complexes. Environmental Science & Technology. ,vol. 41, pp. 1928- 1933 ,(2007) , 10.1021/ES062316Y
Xiu-Sheng Miao, Farida Bishay, Mei Chen, Chris D. Metcalfe, Occurrence of antimicrobials in the final effluents of wastewater treatment plants in Canada. Environmental Science & Technology. ,vol. 38, pp. 3533- 3541 ,(2004) , 10.1021/ES030653Q
Thitima Chuchome, Roongnapa Suedee, Teerapol Srichana, Urairut Kongmark, Use of molecularly imprinted polymers from a mixture of tetracycline and its degradation products to produce affinity membranes for the removal of tetracycline from water. Journal of Chromatography B. ,vol. 811, pp. 191- 200 ,(2004) , 10.1016/J.JCHROMB.2004.08.044
Edwine Tanis, Khalil Hanna, Evens Emmanuel, Experimental and modeling studies of sorption of tetracycline onto iron oxides-coated quartz Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 327, pp. 57- 63 ,(2008) , 10.1016/J.COLSURFA.2008.06.013
Michele E. Lindsey, Michael Meyer, E. M. Thurman, Analysis of Trace Levels of Sulfonamide and Tetracycline Antimicrobials in Groundwater and Surface Water Using Solid-Phase Extraction and Liquid Chromatography/Mass Spectrometry Analytical Chemistry. ,vol. 73, pp. 4640- 4646 ,(2001) , 10.1021/AC010514W
Wen-Tien Tsai, Kuo-Jong Hsien, Hsin-Chieh Hsu, Adsorption of organic compounds from aqueous solution onto the synthesized zeolite. Journal of Hazardous Materials. ,vol. 166, pp. 635- 641 ,(2009) , 10.1016/J.JHAZMAT.2008.11.071
Soh-Fong Lim, Yu-Ming Zheng, Shuai-Wen Zou, J. Paul Chen, Characterization of Copper Adsorption onto an Alginate Encapsulated Magnetic Sorbent by a Combined FT-IR, XPS, and Mathematical Modeling Study Environmental Science & Technology. ,vol. 42, pp. 2551- 2556 ,(2008) , 10.1021/ES7021889