Huge enhancement of photoluminescence emission from porous silicon film doped with Cr(III) ions

作者: Walter J. Salcedo , Mauro S. Braga , Ruth F.V.V. Jaimes

DOI: 10.1016/J.JLUMIN.2018.03.027

关键词:

摘要: Abstract In the present work, it is reported high photoluminescence (PL) enhancement of porous silicon (PS) films doped with Cr+3 ions by electrochemical process. The experimental results showed that PL emission on these samples have been achieved 6 orders magnitude relative to intensity from normal PS sample. peak position takes place below 710 nm suggesting Cr3+ in structure under strong crystal-field action. Raman spectra suggest incorporated at surface forming oxide complex.

参考文章(18)
S.S Jaswal, Electronic structure and properties of transition-metal glasses: NixZr1−x Journal of Non-crystalline Solids. ,vol. 75, pp. 373- 378 ,(1985) , 10.1016/0022-3093(85)90244-3
Olga Syshchyk, Valeriy A. Skryshevsky, Oleksandr O. Soldatkin, Alexey P. Soldatkin, Enzyme biosensor systems based on porous silicon photoluminescence for detection of glucose, urea and heavy metals. Biosensors and Bioelectronics. ,vol. 66, pp. 89- 94 ,(2015) , 10.1016/J.BIOS.2014.10.075
H.A. Lopez, P.M. Fauchet, Infrared LEDs and microcavities based on erbium-doped silicon nanocomposites Materials Science and Engineering B-advanced Functional Solid-state Materials. ,vol. 81, pp. 91- 96 ,(2001) , 10.1016/S0921-5107(00)00744-3
S. Amdouni, M. Rahmani, M.-A Zaïbi, M. Oueslati, Enhancement of porous silicon photoluminescence by electroless deposition of nickel Journal of Luminescence. ,vol. 157, pp. 93- 97 ,(2015) , 10.1016/J.JLUMIN.2014.08.041
Kyu Wang Lee, Patrick E. Hoggard, Relationship of the ruby spectrum to the geometry of the chromium(III) environment Inorganic Chemistry. ,vol. 29, pp. 850- 854 ,(1990) , 10.1021/IC00329A055
M.-B. Bouzourâa, M. Rahmani, M.-A. Zaïbi, N. Lorrain, L. Hajji, M. Oueslati, Optical study of annealed cobalt-porous silicon nanocomposites Journal of Luminescence. ,vol. 143, pp. 521- 525 ,(2013) , 10.1016/J.JLUMIN.2013.05.050
V. Parkhutik, Porous silicon—mechanisms of growth and applications Solid-State Electronics. ,vol. 43, pp. 1121- 1141 ,(1999) , 10.1016/S0038-1101(99)00036-2
Walter Jaimes Salcedo, Francisco J. Ramirez Fernandez, Joel C. Rubim, Changes in the porous silicon structure induced by laser radiation Journal of Raman Spectroscopy. ,vol. 32, pp. 151- 157 ,(2001) , 10.1002/JRS.668
Wing Yin Tong, Martin J. Sweetman, Ezzat R. Marzouk, Cara Fraser, Tim Kuchel, Nicolas H. Voelcker, Towards a subcutaneous optical biosensor based on thermally hydrocarbonised porous silicon. Biomaterials. ,vol. 74, pp. 217- 230 ,(2016) , 10.1016/J.BIOMATERIALS.2015.09.045