Study of vertical Si/SiO2 interface using laser-assisted atom probe tomography and transmission electron microscopy.

作者: J.H. Lee , B.H. Lee , Y.T. Kim , J.J. Kim , S.Y. Lee

DOI: 10.1016/J.MICRON.2013.11.003

关键词:

摘要: Abstract Laser-assisted atom probe tomography has opened the way to three-dimensional visualization of nanostructures. However, many questions related laser–matter interaction remain unresolved. We demonstrate that interface reaction can be activated by laser-assisted field evaporation and affects quantification interfacial composition. At a vertical between Si SiO2, SiO2 molecule tends combine with evaporate as SiO molecule, reducing field. The features depend on direction laser illumination inner structure tip. A high concentration is observed at when column positioned center tip, whereas no significant detected layer center. difference in compositions two samples was due preferential layer. This explained using transmission electron microscopy observations before after experiments.

参考文章(25)
Ralph K. Cavin III, Daniel J.C. Herr, Victor V. Zhirnov, Semiconductor Research Needs in the Nanoscale Physical Sciences: A Semiconductor Research Corporation Working Paper Journal of Nanoparticle Research. ,vol. 2, pp. 213- 235 ,(2000) , 10.1023/A:1010007723640
D. A. Muller, T. Sorsch, S. Moccio, F. H. Baumann, K. Evans-Lutterodt, G. Timp, The electronic structure at the atomic scale of ultrathin gate oxides Nature. ,vol. 399, pp. 758- 761 ,(1999) , 10.1038/21602
D.J. LARSON, B.P. GEISER, T.J. PROSA, S.S.A. GERSTL, D.A. REINHARD, T.F. KELLY, Improvements in planar feature reconstructions in atom probe tomography. Journal of Microscopy. ,vol. 243, pp. 15- 30 ,(2011) , 10.1111/J.1365-2818.2010.03474.X
E. A. MARQUIS, B. P. GEISER, T. J. PROSA, D. J. LARSON, Evolution of tip shape during field evaporation of complex multilayer structures. Journal of Microscopy. ,vol. 241, pp. 225- 233 ,(2011) , 10.1111/J.1365-2818.2010.03421.X
R. Tromp, G. W. Rubloff, P. Balk, F. K. LeGoues, E. J. van Loenen, High-Temperature SiO2Decomposition at the SiO2/Si Interface Physical Review Letters. ,vol. 55, pp. 2332- 2335 ,(1985) , 10.1103/PHYSREVLETT.55.2332
F. Vurpillot, A. Bostel, D. Blavette, Trajectory overlaps and local magnification in three-dimensional atom probe Applied Physics Letters. ,vol. 76, pp. 3127- 3129 ,(2000) , 10.1063/1.126545
Baptiste Gault, Alex La Fontaine, Michael P. Moody, Simon P. Ringer, Emmanuelle A. Marquis, Impact of laser pulsing on the reconstruction in an atom probe tomography. Ultramicroscopy. ,vol. 110, pp. 1215- 1222 ,(2010) , 10.1016/J.ULTRAMIC.2010.04.017
M. Gilbert, W. Vandervorst, S. Koelling, A.K. Kambham, atom probe analysis of a 3D-finfet with high-k metal gate Ultramicroscopy. ,vol. 111, pp. 530- 534 ,(2011) , 10.1016/J.ULTRAMIC.2010.12.025
M. K. Miller, M. G. Hetherington, M. G. Burke, Atom probe field-ion microscopy: A technique for microstructural characterization of irradiated materials on the atomic scale Metallurgical and Materials Transactions A-physical Metallurgy and Materials Science. ,vol. 20, pp. 2651- 2661 ,(1989) , 10.1007/BF02670158
Joseph H. Bunton, Jesse D. Olson, Daniel R. Lenz, Thomas F. Kelly, Advances in pulsed-laser atom probe: instrument and specimen design for optimum performance. Microscopy and Microanalysis. ,vol. 13, pp. 418- 427 ,(2007) , 10.1017/S1431927607070869