Oligonucleotide-templated chemical reactions: pushing the boundaries of a nature-inspired process
作者： Claudia Percivalle , Jean-François Bartolo , Sylvain Ladame
DOI: 10.1039/C2OB26163D
关键词:
摘要: Widespread in nature, oligonucleotide-templated reactions of phosphodiester bond formation have inspired chemists who are now applying this elegant strategy to the catalysis a broad range otherwise inefficient reactions. This review highlights increasing diversity chemical that can be efficiently catalysed by an oligonucleotide template, using Watson–Crick base-pairing bring both reagents close enough proximity react, thus significantly their effective molarity. The applications concept for nucleic acid sensing and controlled organic synthesis will also discussed.
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