作者: V.N. Snytnikov , T.I. Mischenko , Vl.N. Snytnikov , I.G. Chernykh
DOI: 10.1016/J.CEJ.2009.02.028
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摘要: Abstract A flow reactor with the reactants heated by continuous CO 2 laser radiation is proposed for studying gas phase homogeneous reactions. Ethane pyrolysis yielding ethylene considered as an example of such chemical process. For this process, a mode ‘energetic catalysis’ feasible, where increasing energy absorption in volume related increased content target product. The was implemented at transformation into thermal power using sensitization properties ethylene. In reaction zone, temperature measurements were made mixture field density up to 1 0 W/cm . walls and windows isolated from high-temperature zone argon feeding configuration reactor. Three-dimensional calculation gas-dynamic flows their mixing FLUENT software package showed presence modes high C hydrocarbons localized center reactor, which confirmed experiments. High values ethane conversion 80 vol.% obtained nearby 53% selectivity