Comparison of B2O3 and BN deposited by atomic layer deposition for forming ultrashallow dopant regions by solid state diffusion

作者: Steven Consiglio , Robert D. Clark , David O'Meara , Cory S. Wajda , Kandabara Tapily

DOI: 10.1116/1.4928705

关键词:

摘要: In this study, the authors investigated atomic layer deposition (ALD) of B2O3 and BN for conformal, ultrashallow B doping applications compared effect dopant-containing overlayers on sheet resistance (Rs) profiles both types films subjected to a drive-in thermal anneal. For B2O3, tris(dimethylamido)borane O3 were used as coreactants BN, BCl3 NH3 coreactants. Due extreme air instability films, physical analysis was performed which capped in-situ with ∼30 A ALD grown Al2O3 layers. Si3N4 capping layers (∼30 A) comparison. From spectroscopic ellipsometry, thickness decrease observed after 1000 °C, 30 s anneal containing stack 60 cycles whereas stacks showed negligible annealing step, regardless number tested. The postanneal reduction in...

参考文章(37)
Atomic Layer Deposition for Semiconductors Springer Publishing Company, Incorporated. ,(2013) , 10.1007/978-1-4614-8054-9
Bodo Kalkofen, Akinwumi A. Amusan, Marco Lisker, Edmund P. Burte, Application of atomic layer deposited dopant sources for ultra‐shallow doping of silicon Physica Status Solidi (c). ,vol. 11, pp. 41- 45 ,(2014) , 10.1002/PSSC.201300185
B. Mizuno, I. Nakayama, N. Aoi, M. Kubota, T. Komeda, New doping method for subhalf micron trench sidewalls by using an electron cyclotron resonance plasma Applied Physics Letters. ,vol. 53, pp. 2059- 2061 ,(1988) , 10.1063/1.100318
D Lenoble, A Grouillet, The fabrication of advanced transistors with plasma doping Surface and Coatings Technology. ,vol. 156, pp. 262- 266 ,(2002) , 10.1016/S0257-8972(02)00105-6
Wolfgang Skorupa, Rossen A. Yankov, Wolfgang Anwand, Matthias Voelskow, Thoralf Gebel, Daniel F. Downey, Edwin A. Arevalo, Ultra-shallow junctions produced by plasma doping and flash lamp annealing Materials Science and Engineering B-advanced Functional Solid-state Materials. ,vol. 114, pp. 358- 361 ,(2004) , 10.1016/J.MSEB.2004.07.063
Björn Mårlid, Mikael Ottosson, Ulrika Pettersson, Karin Larsson, Jan-Otto Carlsson, Atomic layer deposition of BN thin films Thin Solid Films. ,vol. 402, pp. 167- 171 ,(2002) , 10.1016/S0040-6090(01)01706-0
Bodo Kalkofen, Akinwumi A. Amusan, Muhammad S. K. Bukhari, Bernd Garke, Marco Lisker, Hassan Gargouri, Edmund P. Burte, Use of B2O3 films grown by plasma-assisted atomic layer deposition for shallow boron doping in silicon Journal of Vacuum Science and Technology. ,vol. 33, pp. 031512- ,(2015) , 10.1116/1.4917552
J. Olander, L. M. Ottosson, P. Heszler, J.-O. Carlsson, K. M. E. Larsson, Laser-Assisted Atomic Layer Deposition of Boron Nitride Thin Films Chemical Vapor Deposition. ,vol. 11, pp. 330- 337 ,(2005) , 10.1002/CVDE.200506365
Hervé Dumont, Béatrice Bayle, Bernard Bonnetot, Jean Bouix, Deposition and characterization of BN/Si(0 0 1) using tris(dimethylamino)borane Materials Research Bulletin. ,vol. 37, pp. 1565- 1572 ,(2002) , 10.1016/S0025-5408(02)00844-9
J. Nishizawa, K. Aoki, T. Akamine, Ultrashallow, high doping of boron using molecular layer doping Applied Physics Letters. ,vol. 56, pp. 1334- 1335 ,(1990) , 10.1063/1.103180