Anomalous temperature dependence of the differential capacitance in valence asymmetric electrolytes. Comparison of Monte Carlo simulation results and the field theoretical approach
作者： Dung Di Caprio , Mónika Valiskó , Myroslav Holovko , Dezső Boda
DOI: 10.1080/00268970600976774
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摘要: In this paper, we consider the anomalous behaviour of differential capacitance as a function reduced temperature for case valence asymmetric systems. Monte Carlo simulation results these systems are discussed in view predictions field theoretical approach. We show that simple theory point ions is sufficient to capture main features phenomenon. particular, existence scaling curves related ionic strength well increase peak asymmetry between ions. This indicates important phenomenon essentially electrical properties system.
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D. di Caprio, J. Stafiej, J.P. Badiali, Field theory for ionic systems. From fluctuations and structure at a hard wall to thermodynamics Electrochimica Acta. ,vol. 48, pp. 2967- 2974 ,(2003) , 10.1016/S0013-4686(03)00362-1
Douglas Henderson, Kwong-Yu Chan, Dezső Boda, Monte Carlo study of the capacitance of the double layer in a model molten salt Journal of Chemical Physics. ,vol. 110, pp. 5346- 5350 ,(1999) , 10.1063/1.478429
P. Ballone, G. Pastore, M. P. Tosi, K. R. Painter, P. J. Grout, N. H. March, Dependence of Capacitance of Metal-Molten Salt Interface on Local Density Profiles Near Electrode Physics and Chemistry of Liquids. ,vol. 13, pp. 269- 277 ,(1984) , 10.1080/00319108408080785
Myroslav Holovko, Vitalyj Kapko, Douglas Henderson, Dezsö Boda, On the influence of ionic association on the capacitance of an electrical double layer Chemical Physics Letters. ,vol. 341, pp. 363- 368 ,(2001) , 10.1016/S0009-2614(01)00505-X
G. M. Torrie, J. P. Valleau, Electrical double layers. I. Monte Carlo study of a uniformly charged surface Journal of Chemical Physics. ,vol. 73, pp. 5807- 5816 ,(1980) , 10.1063/1.440065
Dezső Boda, Kwong-Yu Chan, Douglas Henderson, Monte Carlo simulation of an ion-dipole mixture as a model of an electrical double layer Journal of Chemical Physics. ,vol. 109, pp. 7362- 7371 ,(1998) , 10.1063/1.477342
LUIS MIER-Y-TERAN, DEZSŐ BODA, DOUGLAS HENDERSON, SERGIO E. QUIÑONES-CISNEROS, On the low temperature anomalies in the properties of the electrochemical interface. A non-local free-energy density functional approach Molecular Physics. ,vol. 99, pp. 1323- 1328 ,(2001) , 10.1080/00268970110048383
Dezső Boda, Douglas Henderson, Kwong-Yu Chan, Darsh T Wasan, Low temperature anomalies in the properties of the electrochemical interface Chemical Physics Letters. ,vol. 308, pp. 473- 478 ,(1999) , 10.1016/S0009-2614(99)00643-0
L. B. Bhuiyan, C. W. Outhwaite, D. Henderson, A modified Poisson–Boltzmann analysis of the capacitance behavior of the electric double layer at low temperatures The Journal of Chemical Physics. ,vol. 123, pp. 034704- 034704 ,(2005) , 10.1063/1.1992427
J. Reszko-Zygmunt, S. Sokołowski, D. Henderson, D. Boda, Temperature dependence of the double layer capacitance for the restricted primitive model of an electrolyte solution from a density functional approach The Journal of Chemical Physics. ,vol. 122, pp. 084504- 084504 ,(2005) , 10.1063/1.1850453