摘要: The electrochemical behaviour of a series Pb−Sn alloys in 30% sulphuric acid has been studied. Potentiodynamic current transients were recorded for the respective alloys, potential range between hydrogen and oxygen evolution. These carefully studied subsequently correlated with electrochemical, complex plane impedance data. results obtained used to isolate electrode processes prevailing at various potentials determine nature protective films formed, thus elucidating mechanism passivation. Implications corrosion are discussed.
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sci-hub.se 参考文章(28)
Marcel Pourbaix, Atlas of Electrochemical Equilibria in Aqueous Solutions ,(1974)
L.M. Baugh, K.L. Bladen, F.L. Tye, Aspects of the electrochemistry of lead in acid media: Part III. Active dissolution and the active-passive transition in oxygenated and deoxygenated sulphuric acid solutions Journal of Electroanalytical Chemistry. ,vol. 145, pp. 355- 377 ,(1983) , 10.1016/S0022-0728(83)80092-8
Robert H. Cole, On the Analysis of Dielectric Relaxation Measurements Journal of Chemical Physics. ,vol. 23, pp. 493- 499 ,(1955) , 10.1063/1.1742017
B. Ershler, Investigation of electrode reactions by the method of charging-curves and with the aid of alternating currents Discussions of The Faraday Society. ,vol. 1, pp. 269- 277 ,(1947) , 10.1039/DF9470100269
J. H. Sluyters, On the impedance of galvanic cells: V. The impedance of a galvanic cell with two plane parallel electrodes at short distance Recueil des Travaux Chimiques des Pays-Bas. ,vol. 82, pp. 100- 109 ,(2010) , 10.1002/RECL.19630820112
Paul Delahay, Marcel Pourbaix, Pierre Van Rysselberghe, Potential-pH Diagram of Lead and its Applications to the Study of Lead Corrosion and to the Lead Storage Battery Journal of The Electrochemical Society. ,vol. 98, pp. 57- 64 ,(1951) , 10.1149/1.2778106
P. Ruetschi, R. T. Angstadt, Anodic Oxidation of Lead at Constant Potential Journal of The Electrochemical Society. ,vol. 111, pp. 1323- 1330 ,(1964) , 10.1149/1.2425996
J. J. Lander, Some Preliminary Studies of Positive Grid Corrosion in the Lead-Acid Cell Journal of The Electrochemical Society. ,vol. 98, pp. 220- 224 ,(1951) , 10.1149/1.2778135
R.D. Armstrong, K. Edmondson, The impedance of metals in the passive and transpassive regions Electrochimica Acta. ,vol. 18, pp. 937- 943 ,(1973) , 10.1016/0013-4686(73)87025-2
I. Epelboin, M. Keddam, H. Takenouti, Use of impedance measurements for the determination of the instant rate of metal corrosion Journal of Applied Electrochemistry. ,vol. 2, pp. 71- 79 ,(1972) , 10.1007/BF00615194