Optimization of Sucrose Polyester Synthesis Using Response Surface Methodology
作者： CHWEN-JEN SHIEH , PHILIP E. KOEHLER , CASIMIR C. AKOH
DOI: 10.1111/J.1365-2621.1996.TB14734.X
关键词:
摘要: Response Surface Methodology (RSM) was used to evaluate the effects of synthetic variables such as reaction time (6–12 hr), temperature (130–150°C), and substrate molar ratio fatty acid methyl esters (FAME) peanut oil sucrose (10:1 14:1) on % conversion polyester, utilizing 10g free reactant. Optimization performed by canonical analysis derive stationary point. Based contour plots analysis, optimum conditions were: 11.5 hr, 144°C, 11.4:1. Predicted 43.39% (10g synthesized 29.4g polyester) at Experimental data indicated up 48.4% yield based theoretical conversion.
sci-hub.se 参考文章(25)
R. Mead, D. J. Pike, A Biometrics Invited Paper. A Review of Response Surface Methodology from a Biometric Viewpoint Biometrics. ,vol. 31, pp. 803- 851 ,(1975) , 10.2307/2529809
Rebecca S. de la Motte, Maria A. Dean, Frederick W. Wagner, Sugar ester synthesis Sugar ester synthesis.. ,(1988)
Marjorie Mossman Peffly, Larry Nelson Hawkins, Patrick Joseph Corrigan, Corey James Kenneally, Michael Steven Gibson, Production of polyol polyesters having reduced color content Production of polyol polyesters having reduced color content.. ,(1989)
Peter M. Self, Bryan L. Madison, Stephen A. McCoy, David J. Weisgerber, Sucrose polyesters which behave like cocoa butters ,(1988)
Pleun Van Der Plank, Adrianus Rozendaal, Process for preparing partial polyol fatty acid esters ,(1987)
G. E. P. Box, D. W. Behnken, Some New Three Level Designs for the Study of Quantitative Variables Technometrics. ,vol. 2, pp. 455- 475 ,(1960) , 10.1080/00401706.1960.10489912
CASIMIR C. AKOH, BARRY G. SWANSON, BASE CATALYZED TRANSESTERIFICATION OF VEGETABLE OILS 1 Journal of Food Processing and Preservation. ,vol. 12, pp. 139- 149 ,(1988) , 10.1111/J.1745-4549.1988.TB00073.X
CLAIRE MOUQUET, JEAN-CLAUDE DUMAS, STEPHANE GUILBERT, Texturization of Sweetened Mango Pulp: Optimization using Response Surface Methodology Journal of Food Science. ,vol. 57, pp. 1395- 1400 ,(1992) , 10.1111/J.1365-2621.1992.TB06867.X
Norman R. Draper, "RIDGE ANALYSIS" OF RESPONSE SURFACES Technometrics. ,vol. 5, pp. 469- 479 ,(1963) , 10.1080/00401706.1963.10490125
Ronald J. Jandacek, Michele M. Ramirez, John R. Crouse, Effects of partial replacement of dietary fat by olestra on dietary cholesterol absorption in man. Metabolism-clinical and Experimental. ,vol. 39, pp. 848- 852 ,(1990) , 10.1016/0026-0495(90)90131-U