Non-heme manganese complexes of C1-symmetric N4 ligands: Synthesis, characterization and asymmetric epoxidations of α,β-enones
作者： Bin Wang , Cheng-Xia Miao , Shou-Feng Wang , Fritz E. Kühn , Chun-Gu Xia
DOI: 10.1016/J.JORGANCHEM.2012.03.034
关键词:
摘要: Abstract A series of proline-derived C 1 -symmetric chiral tetradentate N ligands and their manganese complexes have been synthesized characterized. Their applications in enantioselective epoxidations α,β-enones were explored reaching good yields up to 71% ee at room temperature.
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