Extraordinary mechanical flexibility in composite thin films composed of bimetallic AgPt nanoparticle-decorated multi-walled carbon nanotubes

作者: Wen-Yin Ko , Jun-Wei Su , Chian-Hua Guo , Kuan-Jiuh Lin

DOI: 10.1016/J.CARBON.2012.01.042

关键词:

摘要: Abstract Flexible, transparent, and conducting composite thin films, constructed from multi-walled carbon-nanotube-supported silver–platinum alloy nanoparticles (AgPt–MWCNT) on a flexible polyethylene terephthalate (PET) substrate through the combination of two-step polyol process for synthesizing composites carbon nanotubes (CNTs) metallic (NPs) with an ultrasonic atomization-spin coating method preparing have been fabricated. AgPt NPs average size approximately 26 nm were uniformly attached to sidewalls MWCNTs form effective strongly mechanical conductive network. These then exposed microwave plasma irradiation, which can lower contact resistance between CNTs reinforce network bridges. The resulting AgPt–MWCNT–PET films exhibit improved optoelectronic properties, they possess sheet 154 Ω/sq transmittance 80% at 550 nm. values are competitive those most other CNT-based films. Most importantly, corresponding conductivity does not decrease even after 500 bending cycles. Therefore, as-produced may be direct alternatives indium tin oxide transparent

参考文章(33)
Alexander Irzh, Isaschar Genish, Lior Klein, Leonid A. Solovyov, Aharon Gedanken, Synthesis of ZnO and Zn nanoparticles in microwave plasma and their deposition on glass slides. Langmuir. ,vol. 26, pp. 5976- 5984 ,(2010) , 10.1021/LA904499S
Fei Xin, Lin Li, Decoration of carbon nanotubes with silver nanoparticles for advanced CNT/polymer nanocomposites Composites Part A-applied Science and Manufacturing. ,vol. 42, pp. 961- 967 ,(2011) , 10.1016/J.COMPOSITESA.2011.03.024
HoSeok Park, Joon-Sung Kim, Bong Gill Choi, Seong Mu Jo, Dong Young Kim, Won Hi Hong, Sung-Yeon Jang, Sonochemical hybridization of carbon nanotubes with gold nanoparticles for the production of flexible transparent conducing films Carbon. ,vol. 48, pp. 1325- 1330 ,(2010) , 10.1016/J.CARBON.2009.11.054
Chuanhong Jin, Kazu Suenaga, Sumio Iijima, Plumbing carbon nanotubes Nature Nanotechnology. ,vol. 3, pp. 17- 21 ,(2008) , 10.1038/NNANO.2007.406
Budhadipta Dan, Glen C. Irvin, Matteo Pasquali, Continuous and scalable fabrication of transparent conducting carbon nanotube films. ACS Nano. ,vol. 3, pp. 835- 843 ,(2009) , 10.1021/NN8008307
Manuela Cano, Ana Benito, Wolfgang K. Maser, Esteban P. Urriolabeitia, One-step microwave synthesis of palladium–carbon nanotube hybrids with improved catalytic performance Carbon. ,vol. 49, pp. 652- 658 ,(2011) , 10.1016/J.CARBON.2010.10.012
H Conrads, M Schmidt, Plasma generation and plasma sources Plasma Sources Science and Technology. ,vol. 9, pp. 441- 454 ,(2000) , 10.1088/0963-0252/9/4/301
Chuen-Yuan Hsu, Kuan-Jiuh Lin, Wen-Yin Ko, Jun-Wei Su, Chian-Hua Guo, Shu-Juan Fu, Highly conductive, transparent flexible films based on open rings of multi-walled carbon nanotubes Thin Solid Films. ,vol. 519, pp. 7717- 7722 ,(2011) , 10.1016/J.TSF.2011.05.064
Bo Hu, Shang-Bing Wang, Kan Wang, Meng Zhang, Shu-Hong Yu, Microwave-assisted rapid facile "Green" synthesis of uniform silver nanoparticles: Self-assembly into multilayered films and their optical properties Journal of Physical Chemistry C. ,vol. 112, pp. 11169- 11174 ,(2008) , 10.1021/JP801267J