Behavior of Rydberg atoms at surfaces: energy level shifts and ionization
作者： F.B Dunning , H.R Dunham , C Oubre , P Nordlander
DOI: 10.1016/S0168-583X(02)02176-6
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摘要: The ionization of xenon atoms excited to the extreme red and blue states in high-lying Xe(n) Stark manifolds at a metal surface is investigated. data show that, despite their very different initial spatial characteristics, members given manifold ionize similar atom/surface separations. This explained, with aid complex scaling calculations, terms strong perturbations energies structure atomic induced by presence which lead avoided crossings between neighboring levels as approached.
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