Preparation and characterization of polythiophene/molybdenum disulfide intercalation material

作者: Bi-Zhou Lin , Cong Ding , Bai-Huan Xu , Zhi-Jian Chen , Yi-Lin Chen

DOI: 10.1016/J.MATERRESBULL.2008.09.031

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摘要: Abstract Utilizing the solvothermal synthesis technique, lithium intercalated molybdenum disulfide LixMoS2 was expediently obtained, which allowed to react with water formation of single-molecule-layer suspension. The intercalation polythiophene into MoS2 achieved by means in situ polymerization monomers. nanocomposite characterized X-ray powder diffraction, thermogravimertic analysis and differential scanning calorimetry. It revealed that polymer chain favors monolayer arrangement thiophene rings lying parallel host layers. optimum conditions were explored prepare single-phase product a composition Li0.12(PTP)0.54MoS2. exhibits enhanced electrical conductivity order 10−2 S cm−1 at ambient temperature, resulted from incorporation electronically conductive between semiconducting layers coupling guest conjugated π-orbits

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