Synthesis and nanostructural characterization of new layered compounds based on molybdenum disulfide and organic dyes
作者： Alexandre S. Golub , Natalia D. Lenenko , Vladimir I. Zaikovskii , Yurii N. Novikov
DOI: 10.1016/J.SOLIDSTATESCIENCES.2011.10.016
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摘要: Abstract Preparation of new MoS2 layered compounds, in which organic dyes (rhodamine 6G, oxazine 1, and thionine) were used as the guest components, was successfully realized two reaction systems differing by nature molybdenum disulfide. In one system, form single-layer dispersion aqueous media; other it taken nanodispersed powdered material, res-MoS2, obtained exfoliation-restacking procedure suspended non-aqueous solvent. Structures prepared compounds are discussed on basis their compositions, X-ray diffraction high-resolution transmission electron microscopy data. The hybrid formed dispersions found to contain layers, each alternate with dye layer, whereas, case res-MoS2 same well sequences inorganic layers depending conditions. vicinity different-thickness domains revealed within rhodamine oxazine. It results from different packings molecules sufficient flexibility disulfide layers.
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