DSC and thermal imaging studies of methane hydrate formation and dissociation in water emulsions in crude oils
作者： M. E. Semenov , A. Yu. Manakov , E. Yu. Shitz , A. S. Stoporev , L. K. Altunina
DOI: 10.1007/S10973-014-4203-7
关键词:
摘要: The processes of methane hydrate formation from 50 mass% water-in-oil emulsion the Mamontovskoe, Sovetskoe, Van-Eganskoe, and Vakhskoe oil deposits (East Siberia) were studied using differential scanning calorimetry. It was shown that different types thermal effects may be observed in curves corresponding to (and/or ice) emulsions. In particular on curves, we appearance a single asymmetric effect or set large number separate small effects. analysis results allowed us conclude (ice freezing) emulsions occurs as collective process, which involves lot water droplets This process some space inside sample. volume this determines type curve recorded experiment. Secondary nucleation (nucleation solid phase due contact drop with neighboring ice particle) enables fast gas all space.
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sci-hub.se 参考文章(33)
Bahman Tohidi, Novel hydrate based systems ,(2005)
D. Dalmazzone, M. Kharrat, V. Lachet, B. Fouconnier, D. Clausse, DSC and PVT measurements Journal of Thermal Analysis and Calorimetry. ,vol. 70, pp. 493- 505 ,(2002) , 10.1023/A:1021632709287
Johan Sjöblom, Bodhild Øvrevoll, GunnHeidi Jentoft, Caterina Lesaint, Thierry Palermo, Anne Sinquin, Patrick Gateau, Loïc Barré, Siva Subramanian, John Boxall, Simon Davies, Laura Dieker, David Greaves, Jason Lachance, Patrick Rensing, Kelly Miller, E. Dendy Sloan, Carolyn A. Koh, Investigation of the Hydrate Plugging and Non-Plugging Properties of Oils Journal of Dispersion Science and Technology. ,vol. 31, pp. 1100- 1119 ,(2010) , 10.1080/01932690903224698
Didier Dalmazzone, Néjib Hamed, Christine Dalmazzone, DSC measurements and modelling of the kinetics of methane hydrate formation in water-in-oil emulsion Chemical Engineering Science. ,vol. 64, pp. 2020- 2026 ,(2009) , 10.1016/J.CES.2009.01.028
Dimo Kashchiev, Abbas Firoozabadi, Induction time in crystallization of gas hydrates Journal of Crystal Growth. ,vol. 250, pp. 499- 515 ,(2003) , 10.1016/S0022-0248(02)02461-2
A. Yu. Manakov, L. S. Aladko, A. G. Ogienko, A. I. Ancharov, Hydrate formation in the system n -propanol–water Journal of Thermal Analysis and Calorimetry. ,vol. 111, pp. 885- 890 ,(2013) , 10.1007/S10973-012-2246-1
Simon R. Davies, Keith C. Hester, Jason W. Lachance, Carolyn A. Koh, E. Dendy Sloan, Studies of hydrate nucleation with high pressure differential scanning calorimetry Chemical Engineering Science. ,vol. 64, pp. 370- 375 ,(2009) , 10.1016/J.CES.2008.10.017
Olga V. Gafonova, Harvey W. Yarranton, The Stabilization of Water-in-Hydrocarbon Emulsions by Asphaltenes and Resins joint international conference on information sciences. ,vol. 241, pp. 469- 478 ,(2001) , 10.1006/JCIS.2001.7731
Bahman Tohidi, Antonin Chapoy, Jinhai Yang, Developing a Hydrate-Monitoring System Spe Projects Facilities & Construction. ,vol. 4, pp. 1- 6 ,(2009) , 10.2118/125130-PA
Askar K Gatiatulin, Marat A Ziganshin, Valery V Gorbatchuk, None, Selective preparation of beta-cyclodextrin clathrates by solid-phase exchange of included tetrahydrofurane for volatile guests in absence of water Journal of Thermal Analysis and Calorimetry. ,vol. 118, pp. 987- 992 ,(2014) , 10.1007/S10973-014-3800-9