Selective carbonylation of dimethyl ether to methyl acetate on Ferrierite

作者: So Young Park , Chae-Ho Shin , Jong Wook Bae

DOI: 10.1016/J.CATCOM.2015.12.006

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摘要: Abstract Synthesis of methyl acetate (MA) by carbonylation dimethyl ether (DME) was investigated using laboratory-made H-form Ferrierite (FER) zeolite with different Si/Al molar ratios. The synthesized H-FER a ratio 12 (FER(12)) revealed higher DME conversion as well MA selectivity. observed catalytic performance on the FER(12) mainly attributed to Bronsted Lewis acid sites crystallinity less coke formation. superior properties having and efficiently suppressed formation inactive precursors.

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