Quantitative gas chromatographic analysis on support-coated open tubular capillary columns

作者: Rex W. Souter , Rafik H. Bishara

DOI: 10.1016/S0021-9673(00)93583-0

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摘要: Gas chromatographic methodology has been developed for quantitative analysis of samples o-, m-, and p-ethylphenols. Samples are dissolved in a dichloromethane solution the internal standard, anisole, then derivatized with N-trimethylsilylimidazole to form silyl ethers. The chromatographed similarly prepared standards on stainless-steel OV-17 support-coated open tubular (SCOT) column. Specificity, linearity, precision stability discussed, chromatograms obtained SCOT column compared those packed analytical column. This report describes one first gas methods use (capillary) column.

参考文章(14)
B.L. Goodwin, C.R.J. Ruthven, M. Sandler, Gas chromatographic estimation of urinary homovanillic and 4-hydroxy-3-methoxymandelic acids using capillary columns. Clinica Chimica Acta. ,vol. 55, pp. 111- 112 ,(1974) , 10.1016/0009-8981(74)90342-8
P.M. Cain, Comparison of kerosenes using capillary column gas liquid chromatography. Journal of The Forensic Science Society. ,vol. 15, pp. 301- 308 ,(1975) , 10.1016/S0015-7368(75)71003-4
K. D. Bartle, M. L. Lee, M. Novotny, High-Resolution GLC Profiles of Urban Air Pollutant Polynuclear Aromatic Hydrocarbons International Journal of Environmental Analytical Chemistry. ,vol. 3, pp. 349- 356 ,(1974) , 10.1080/03067317408071095
Willem Krijgsman, Cornelis G. Van De Kamp, Determination of chlorophenols by capillary gas chromatography Journal of Chromatography A. ,vol. 131, pp. 412- 416 ,(1977) , 10.1016/S0021-9673(00)80960-7
N.K. McCallum, E.R. Cairns, Simple device for GLC separations of cannabinoids using a surface-coated open tube column without stream splitting. Journal of Pharmaceutical Sciences. ,vol. 66, pp. 114- 116 ,(1977) , 10.1002/JPS.2600660131
Willem Krijgsman, Cornelis G. Van De Kamp, Analysis of organophosphorus pesticides by capillary gas chromatography with flame photometric detection Journal of Chromatography A. ,vol. 117, pp. 201- 205 ,(1976) , 10.1016/S0021-9673(00)81084-5
M. Stafford, M.G. Horning, A. Zlatkis, Profiles of volatile metabolites in body fluids Journal of Chromatography A. ,vol. 126, pp. 495- 502 ,(1976) , 10.1016/S0021-9673(01)84096-6