Structural, optical and electrical properties of CuInS2 thin films prepared by chemical spray pyrolysis
作者： Tomoaki Terasako , Yuji Uno , Seiki Inoue , Tetsuya Kariya , Sho Shirakata
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摘要: Polycrystalline CuInS2 thin films were prepared by chemical spray pyrolisis (CSP) on glass sustrate from the ethanol aqueous solution containing CuCl2, InCl3 and thiourea. Structual, electrical optical properties systematically studied in terms of substrate temperature, pH ion ratio (Cu/In) solution. Although In-rich composed In2S3, In2S3 content film decreased with Cu/In ratio. Appearance Raman peaks at 288 298 cm-1 indicated that contained chalcopyrite CuAu phases. Typical grain size Cu-rich was 200 nm. Optical gap energies approximately 0.1-0.2eV smaller than bandgap energy bulk crystal. Resisitivity without secondary phase 0.2–5 Ωcm. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)
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sci-hub.se 参考文章(10)
J. L. Queisser, J. H. Wernick, Archibald L. Fripp, Ternary Chalcopyrite Semiconductors: Growth, Electronic Properties, and Applications Journal of The Electrochemical Society. ,vol. 123, ,(1976) , 10.1149/1.2132889
Sho Shirakata, Yoshiaki Kannaka, Harufumi Hasegawa, Tetsuya Kariya, Shigehiro Isomura, Properties of Cu(In,Ga)Se2 Thin Films Prepared by Chemical Spray Pyrolysis Japanese Journal of Applied Physics. ,vol. 38, pp. 4997- 5002 ,(1999) , 10.1143/JJAP.38.4997
Sho Shirakata, Tomonori Murakami, Tetsuya Kariya, Shigehiro Isomura, Preparation ofCuInSe2Thin Films by Chemical Spray Pyrolysis Japanese Journal of Applied Physics. ,vol. 35, pp. 191- 199 ,(1996) , 10.1143/JJAP.35.191
T TERASAKO, Y UNO, T KARIYA, S SHIRAKATA, Structural and optical properties of In-rich Cu–In–Se polycrystalline thin films prepared by chemical spray pyrolysis Solar Energy Materials and Solar Cells. ,vol. 90, pp. 262- 275 ,(2006) , 10.1016/J.SOLMAT.2005.03.010
I. Oja, M. Nanu, A. Katerski, M. Krunks, A. Mere, J. Raudoja, A. Goossens, Crystal quality studies of CuInS2 films prepared by spray pyrolysis Thin Solid Films. ,vol. 480, pp. 82- 86 ,(2005) , 10.1016/J.TSF.2004.11.013
A.N. Tiwari, D.K. Pandya, K.L. Chopra, Electrical and optical properties of single-phase CuInS2 films prepared using spray pyrolysis Thin Solid Films. ,vol. 130, pp. 217- 230 ,(1985) , 10.1016/0040-6090(85)90353-0
Eveline Rudigier, Beatriz Barcones, Ilka Luck, T. Jawhari-Colin, Alejandro Pérez-Rodrı́guez, Roland Scheer, Quasi real-time Raman studies on the growth of Cu-In-S thin films Journal of Applied Physics. ,vol. 95, pp. 5153- 5158 ,(2004) , 10.1063/1.1667009
Sho Shirakata, Tomoaki Terasako, Tetsuya Kariya, Properties of CuIn(SxSe1−x)2 polycrystalline thin films prepared by chemical spray pyrolysis Journal of Physics and Chemistry of Solids. ,vol. 66, pp. 1970- 1973 ,(2005) , 10.1016/J.JPCS.2005.09.091
Malle Krunks, Olga Bijakina, Tiit Varema, Valdek Mikli, Enn Mellikov, Structural and optical properties of sprayed CuInS2 films Thin Solid Films. ,vol. 338, pp. 125- 130 ,(1999) , 10.1016/S0040-6090(98)01069-4
Sho Shirakata, Hitoshi Kubo, Chihiro Hamaguchi, Shigehiro Isomura, Raman Spectra of CuInSe 2 Thin Films Prepared by Chemical Spray Pyrolysis Japanese Journal of Applied Physics. ,vol. 36, ,(1997) , 10.1143/JJAP.36.L1394