Carbon dioxide as a solubility "switch" for the reversible dissolution of highly fluorinated complexes and reagents in organic solvents: application to crystallization.

作者: Philip G. Jessop , Marilyn M. Olmstead , Christopher D. Ablan , Megan Grabenauer , Daniel Sheppard

DOI: 10.1021/IC020057H

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摘要: … Subsequently releasing the gas causes the compounds to precipitate or crystallize, giving quantitative recovery of the solid. The resulting crystals can be of sufficient quality for single-…

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