Use and recovery of a homogeneous catalyst with carbon dioxide as a solubility switch

作者: Christopher D. Ablan , Jason P. Hallett , Kevin N. West , Rebecca S. Jones , Charles A. Eckert

DOI: 10.1039/B311146F

关键词:

摘要: A method for fluorous biphasic catalysis is described, in which the liquid replaced by fluorinated silica, catalyst induced to dissolve organic solvent presence of CO2, and recovery after reaction achieved release CO2 pressure.

参考文章(11)
Philip G. Jessop, Marilyn M. Olmstead, Christopher D. Ablan, Megan Grabenauer, Daniel Sheppard, Charles A. Eckert, Charles L. Liotta, Carbon dioxide as a solubility "switch" for the reversible dissolution of highly fluorinated complexes and reagents in organic solvents: application to crystallization. Inorganic Chemistry. ,vol. 41, pp. 3463- 3468 ,(2002) , 10.1021/IC020057H
Elwin de Wolf, Gerard van Koten, Berth-Jan Deelman, Fluorous phase separation techniques in catalysis Chemical Society Reviews. ,vol. 28, pp. 37- 41 ,(1999) , 10.1039/A805644G
Victor Chechik, Richard M. Crooks, Dendrimer-Encapsulated Pd Nanoparticles as Fluorous Phase-Soluble Catalysts Journal of the American Chemical Society. ,vol. 122, pp. 1243- 1244 ,(2000) , 10.1021/JA9936870
Bodo Richter, Anthony L. Spek, Gerard van Koten, Berth-Jan Deelman, Fluorous Versions of Wilkinson's Catalyst : Activity in Fluorous Hydrogenation of 1-Alkenes and Recycling by Fluorous Biphasic Separation Journal of the American Chemical Society. ,vol. 122, pp. 3945- 3951 ,(2000) , 10.1021/JA993562V
Drew Rutherford, Jerrick J.J. Juliette, Christian Rocaboy, István T. Horváth, J.A. Gladysz, Transition metal catalysis in fluorous media: Application of a new immobilization principle to rhodium-catalyzed hydrogenation of alkenes Catalysis Today. ,vol. 42, pp. 381- 388 ,(1998) , 10.1016/S0920-5861(98)00120-5
Eric G Hope, Ray D.W Kemmitt, Danny R Paige, Alison M Stuart, THE RHODIUM CATALYSED HYDROGENATION OF STYRENE IN THE FLUOROUS BIPHASE Journal of Fluorine Chemistry. ,vol. 99, pp. 197- 200 ,(1999) , 10.1016/S0022-1139(99)00183-9
KP Hafner, SL Yun, F Deng, SG Kazarian, CL Liotta, CA Eckert, Cosolvent tuning of tautomeric equilibrium in supercritical fluids AIChE Journal. ,vol. 43, pp. 515- 524 ,(1997) , 10.1002/AIC.690430224