Stabilization of the ζ-Cu10Sn3 Phase by Ni at Soldering-Relevant Temperatures

作者: C. Wieser , W. Hügel , S. Martin , J. Freudenberger , A. Leineweber

DOI: 10.1007/S11664-020-08036-7

关键词:

摘要: A current issue in electrical engineering is the enhancement of quality solder joints. This mainly associated with ongoing electrification transportation as well miniaturization (power) electronics. For reliability joints, intermetallic phases microstructure are great importance. The formation Cu-Sn system was investigated for different annealing temperatures between 472 K and 623 K using pure Cu Cu-1at.%Ni Cu-3at.%Ni substrate materials. These relevant lead frame materials electronic components. Cu-Ni alloys were contact to galvanic plated Sn. work focused on unexpected hexagonal ζ-(Cu,Ni)10Sn3 phase at 523–623 K, which far below eutectoid decomposition temperature binary ζ-Cu10Sn3 about 855 K. By scanning electron microscopy, energy dispersive X-ray spectroscopy, backscatter diffraction presence ζ confirmed its structural properties analyzed.

参考文章(40)
D.K. Mu, S.D. McDonald, J. Read, H. Huang, K. Nogita, Critical properties of Cu6Sn5 in electronic devices: Recent progress and a review Current Opinion in Solid State & Materials Science. ,vol. 20, pp. 55- 76 ,(2016) , 10.1016/J.COSSMS.2015.08.001
Guang Zeng, Stuart D. McDonald, Qinfen Gu, Yasuko Terada, Kentaro Uesugi, Hideyuki Yasuda, Kazuhiro Nogita, The influence of Ni and Zn additions on microstructure and phase transformations in Sn–0.7Cu/Cu solder joints Acta Materialia. ,vol. 83, pp. 357- 371 ,(2015) , 10.1016/J.ACTAMAT.2014.10.003
W. Lawrence Bragg, XLII. The crystalline structure of copper Philosophical Magazine Series 1. ,vol. 28, pp. 355- 360 ,(1914) , 10.1080/14786440908635219
Dekui Mu, Jonathan Read, Yafeng Yang, Kazuhiro Nogita, None, Thermal expansion of Cu6Sn5 and (Cu,Ni)6Sn5 Journal of Materials Research. ,vol. 26, pp. 2660- 2664 ,(2011) , 10.1557/JMR.2011.293
Kazuhiro Nogita, Stuart D. McDonald, Hideaki Tsukamoto, Jonathan Read, Shoichi Suenaga, Tetsuro Nishimura, Inhibiting Cracking of Interfacial Cu6Sn5 by Ni Additions to Sn-based Lead-free Solders Transactions of The Japan Institute of Electronics Packaging. ,vol. 2, pp. 46- 54 ,(2009) , 10.5104/JIEPENG.2.46
T.E. Konstantinova, V.I. Zaitsev, Reversible temper embrittlement in a steel deformed under high pressure Materials Science and Engineering. ,vol. 49, pp. 1- 6 ,(1981) , 10.1016/0025-5416(81)90127-0
Koichi Momma, Fujio Izumi, VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data Journal of Applied Crystallography. ,vol. 44, pp. 1272- 1276 ,(2011) , 10.1107/S0021889811038970
Y. Watanabe, Y. Fujinaga, H. Iwasaki, Lattice modulation in the long-period superstructure of Cu3Sn Acta Crystallographica Section B-structural Science. ,vol. 39, pp. 306- 311 ,(1983) , 10.1107/S0108768183002451