Multicomponent high-pressure adsorption equilibria on carbon substrates: Theory and data
作者： Anthony E. DeGance
DOI: 10.1016/0378-3812(92)87031-H
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摘要: Abstract DeGance A.E., 1992. Multicomponent high-pressure adsorption equilibria on carbon substrates: theory and data. Fluid Phase Equilibria, 78: 99-137. We explore the two-dimensional equation of state representation multicomponent isotherm, building research de Boer, Kobayashi Leiand. formulate so that knowledge surface area is unnecessary. For wet coal substrates at high pressure, we find EOS may be more accurate than either ideal adsorbed solution Prausnitz Myers or generalized Langmuir theory. The calculation requires simultaneous fugacity equations together with mole balance equations; this computation non-trivial. introduce a path-continuation approach, namely loading composition homotopy, to solve complex equilibrium equations. homotopy parameter naturally embedded in problem. This distinguishes our homotopies from others.
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