Komplexbildung mit Aminophosphinen. IX. Vier- und fünffach koordinierte Komplexverbindungen des Nickels mit N, N-Bis(diphenylphosphino)anilin†
作者： W. Seidel , M. Alexiev
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摘要: Die Synthese des leicht zuganglichen Diphosphinoanilins, PhN(PPh2)2, und verschiedene Typen seiner Chelatkomplexe mit Nickel(II) werden beschrieben. Der Ligand (NP2) bildet planare Komplexe [(NP2)NiX2] (X = Cl, Br, I, NCS) [Ni(NP2)2](ClO4)2 sowie die funffach koordinierten Verbindungen [(NP2)2NiX]ClO4. Fur letzteren wird eine quadratisch-pyramidale Struktur angenommen. Complex Formation with Aminophosphines. IX. Fourfold and Fivefold Coordinated Complexes of the Bidentate N, N-Bis(diphenylphosphino)phenylamine The preparation characterization ligand PhN(PPh2)2 some its nickel complexes are reported. The forms stable planar [Ni(NP2)2](ClO4)2, pentacoordinated, square-pyramidal
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