Dynamic kinetic resolution of bis-aryl succinic anhydrides: enantioselective synthesis of densely functionalised γ-butyrolactones
作者： Romain Claveau , Brendan Twamley , Stephen J. Connon
DOI: 10.1039/C8CC00609A
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摘要: The efficient Dynamic Kinetic Resolution (DKR) of disubstituted anhydrides has been shown to be possible for the first time. Using an ad hoc designed organocatalyst and enantio- diastereoselective cycloaddition process with aldehydes, stereochemically complex γ-butyrolactone derivatives can obtained - control over three contiguous stereocentres, one which is all carbon quaternary.
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