Iron Contamination Mechanism and Reaction Performance Research on FCC Catalyst

作者: Zhaoyong Liu , Zhongdong Zhang , Pusheng Liu , Jianing Zhai , Chaohe Yang

DOI: 10.1155/2015/273859

关键词:

摘要: FCC (Fluid Catalytic Cracking) catalyst iron poisoning would not only influence units’ product slate; when the is serious, it could also jeopardize catalysts’ fluidization in reaction-regeneration system and further cause bad influences on stable operation. Under catalytic cracking reaction conditions, large amount of nanonodules formed seriously contaminated due to exothermic reaction. These nodules intensify attrition between particles generate plenty fines which severely smooth running. A dense layer be surface after contamination stops reactants diffuse inner structures catalyst. This causes extremely negative effects catalyst’s heavy oil conversion ability greatly cut down gasoline yield while increasing yields dry gas, coke, slurry largely. Research shows that performance deteriorated content E-cat (equilibrium catalyst) exceeds 8000 μg/g.

参考文章(9)
Bradley Merril Patten, Petroleum Refinery Engineering ,(1941)
Yannick Mathieu, Avelino Corma, Michaël Echard, Marc Bories, Single and combined fluidized catalytic cracking (FCC) catalyst deactivation by iron and calcium metal-organic contaminants Applied Catalysis A-general. ,vol. 469, pp. 451- 465 ,(2014) , 10.1016/J.APCATA.2013.10.007
H.S. Cerqueira, G. Caeiro, L. Costa, F. Ramôa Ribeiro, Deactivation of FCC catalysts Journal of Molecular Catalysis A-chemical. ,vol. 292, pp. 1- 13 ,(2008) , 10.1016/J.MOLCATA.2008.06.014
Bipin V. Vora, Development of Dehydrogenation Catalysts and Processes Topics in Catalysis. ,vol. 55, pp. 1297- 1308 ,(2012) , 10.1007/S11244-012-9917-9
A.M Brass, J Chene, Influence of deformation on the hydrogen behavior in iron and nickel base alloys: a review of experimental data Materials Science and Engineering A-structural Materials Properties Microstructure and Processing. ,vol. 242, pp. 210- 221 ,(1998) , 10.1016/S0921-5093(97)00523-6
D. Wallenstein, D. Farmer, J. Knoell, C.M. Fougret, S. Brandt, Progress in the deactivation of metals contaminated FCC catalysts by a novel catalyst metallation method Applied Catalysis A-general. pp. 91- 99 ,(2013) , 10.1016/J.APCATA.2013.02.002
Haohua Gao, Gang Wang, Chunming Xu, Jinsen Gao, Eight-Lump Kinetic Modeling of Vacuum Residue Catalytic Cracking in an Independent Fluid Bed Reactor Energy & Fuels. ,vol. 28, pp. 6554- 6562 ,(2014) , 10.1021/EF501260N
Du Quan-sheng Zhu Yu-xia Lin Wei Long Jun, STUDIES OF THE IRON POISON ON THE FCC CATALYSTS Acta Petrolei Sinica(Petroleum Processing Section). ,vol. 23, pp. 37- ,(2007)
Sinopec Catalyst, INFLUENCE OF IRON ON CATALYTIC CRACKING CATALYST Qilu Petrochemical Technology. ,(2012)