Stabilization/Solidification of Toxic Elements in Cement Pastes Containing a Spent FCC Catalyst

作者: Jefferson Santos Silva , Heloysa Martins Carvalho Andrade , Jardel Pereira Gonçalves , Kelly Rodrigues dos Santos

DOI: 10.1007/S11270-021-05015-4

关键词: Hazardous wasteLeaching (metallurgy)ContaminationToxicity characteristic leaching procedureFluid catalytic crackingMetallurgyCementVanadiumMaterials scienceLeachate

摘要: Huge amounts of spent fluid catalytic cracking (FCC) catalysts, also called Ecat, are produced worldwide, every year. Alternatives to the traditional landfill disposal imperative reduce environmental contamination and production hazardous solid wastes. The leaching iron, nickel, antimony, vanadium from Ecat was investigated using toxicity characteristic procedure (TCLP) assess risk aquatic environment. concentrations these elements in leachate a cement paste containing 15% were much reduced as compared those leached sample below limits established water quality criteria United States Environmental Protection Agency (USEPA 2004). solidification/stabilization (S/S) Fe, Ni, V, Sb influenced by chemical properties stability products formed with cement-hydrated phases erosion exposed environments. S/S mechanisms less effective seawater this related reactions salts usually present seawater. results indicated that process efficient enough prevent excessive toxic elements.

参考文章(71)
Francisco Gabriel Santos Silva, Raildo Alves Fiuza Junior, Jefferson Santos da Silva, Carlos Magno S. R. de Brito, Heloysa Martins Carvalho Andrade, Jardel Pereira Gonçalves, Consumption of calcium hydroxide and formation of C–S–H in cement pastes Journal of Thermal Analysis and Calorimetry. ,vol. 116, pp. 287- 293 ,(2014) , 10.1007/S10973-013-3546-9
Alan Earnshaw, Norman Neill Greenwood, Chemistry of the elements ,(1984)
Paul B. Venuto, E. Thomas Habib, Fluid Catalytic Cracking with Zeolite Catalysts ,(1979)
Zhaoyong Liu, Zhongdong Zhang, Pusheng Liu, Jianing Zhai, Chaohe Yang, Iron Contamination Mechanism and Reaction Performance Research on FCC Catalyst Journal of Nanotechnology. ,vol. 2015, pp. 1- 6 ,(2015) , 10.1155/2015/273859
Beibei Dai, Cheng Chao, Xiaoyu Lu, Qingcheng Xia, Jing Han, Fei Mao, Jiazhi Yang, Dongping Sun, Preparation of ZnO/CdS/BC Photocatalyst Hybrid Fiber and Research of Its Photocatalytic Properties Journal of Nanotechnology. ,vol. 2015, pp. 1- 8 ,(2015) , 10.1155/2015/614170
Liping Fang, Wentao Li, Huimin Chen, Feng Xiao, Lizhi Huang, Peter E. Holm, Hans Christian B. Hansen, Dongsheng Wang, Synergistic effect of humic and fulvic acids on Ni removal by the calcined Mg/Al layered double hydroxide RSC Advances. ,vol. 5, pp. 18866- 18874 ,(2015) , 10.1039/C4RA15406A
Mohamad Johari Abu, Julie Juliewatty Mohamed, Zainal Arifin Ahmad, Synthesis of high purity titanium silicon carbide from elemental powders using arc melting method International Journal of Refractory Metals & Hard Materials. ,vol. 47, pp. 86- 92 ,(2014) , 10.1016/J.IJRMHM.2014.06.022
J. Payá, M. V. Borrachero, J. Monzó, L. Soriano, Estudio del comportamiento de diversos residuos de catalizadores de craqueo catalítico (FCC) en cemento Portland Materiales De Construccion. ,vol. 59, pp. 37- 52 ,(2009) , 10.3989/MC.2009.48108
Oguz Bayraktar, Edwin L. Kugler, Visualization of the Equilibrium FCC Catalyst Surface by AFM and SEM–EDS Catalysis Letters. ,vol. 90, pp. 155- 160 ,(2003) , 10.1023/B:CATL.0000004110.98820.D9