Hydrogenases as Catalysts in Renewable Energy Applications
作者： Jesse W. Tye , Michael B. Hall
DOI: 10.1002/9781119951438.EIBC2157
关键词:
摘要: This review details the role of hydrogenase enzymes in development new electrode materials for proton reduction and dihydrogen oxidation. Platinum is best catalyst these reactions, but it expensive rare. Graphite electrodes functionalized by are one possible route to synthesis inexpensive water splitting based on common, earth-abundant elements. The major shortcoming there extreme sensitivity oxygen. Experimental theoretical study mechanisms reduction, hydrogen oxidation, oxygen inactivation discussed. Natural synthetic methods increasing tolerance also discussed. Keywords: hydrogenases; hydrogen production; hydrogen oxidation; proton reduction; biomimetic chemistry; electrochemistry; catalyst inactivation; catalysis; water
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