Effect of temperature, duration and speed of pre-mixing on the dispersion of clay/epoxy nanocomposites

作者: T.-D. Ngo , M.-T. Ton-That , S.V. Hoa , K.C. Cole

DOI: 10.1016/J.COMPSCITECH.2009.03.024

关键词:

摘要: The effect of temperature, duration and speed pre-mixing on the dispersion organoclay in epoxy was studied. technique high-speed mixing process used. Epoxy Cloisite 30B were pre-mixed at different temperatures, speeds for durations time. quality intercalation/exfoliation after (before adding hardener) analyzed by means X-ray diffraction (XRD) viscosity measurement. nanocomposites (ENCs) curing characterized XRD, field emission gun scanning electron microscopy (FEGSEM) TEM. results illustrate that clay particles broken down to smaller sizes with increase temperature especially speed. These parameters do not significantly affect step, but they have indirect step.

参考文章(14)
Janis M. Brown, David Curliss, Richard A. Vaia, Thermoset-Layered Silicate Nanocomposites. Quaternary Ammonium Montmorillonite with Primary Diamine Cured Epoxies Chemistry of Materials. ,vol. 12, pp. 3376- 3384 ,(2000) , 10.1021/CM000477+
Phillip B. Messersmith, Emmanuel P. Giannelis, Synthesis and Characterization of Layered Silicate-Epoxy Nanocomposites Chemistry of Materials. ,vol. 6, pp. 1719- 1725 ,(1994) , 10.1021/CM00046A026
Weiping Liu, Suong V. Hoa, Martin Pugh, Morphology and performance of epoxy nanocomposites modified with organoclay and rubber Polymer Engineering and Science. ,vol. 44, pp. 1178- 1186 ,(2004) , 10.1002/PEN.20111
Weiping Liu, Suong V. Hoa, Martin Pugh, Organoclay-modified high performance epoxy nanocomposites Composites Science and Technology. ,vol. 65, pp. 307- 316 ,(2005) , 10.1016/J.COMPSCITECH.2004.07.012
Tie Lan, Thomas J. Pinnavaia, Clay-Reinforced Epoxy Nanocomposites Chemistry of Materials. ,vol. 6, pp. 2216- 2219 ,(1994) , 10.1021/CM00048A006
H. Wang, S. V. Hoa, P. M. Wood-Adams, New method for the synthesis of clay/epoxy nanocomposites Journal of Applied Polymer Science. ,vol. 100, pp. 4286- 4296 ,(2006) , 10.1002/APP.23859
Jyi-Jiin Luo, Isaac M Daniel, Characterization and modeling of mechanical behavior of polymer/clay nanocomposites Composites Science and Technology. ,vol. 63, pp. 1607- 1616 ,(2003) , 10.1016/S0266-3538(03)00060-5
X Kornmann, H Lindberg, Lars A Berglund, Synthesis of epoxy–clay nanocomposites. Influence of the nature of the curing agent on structure Polymer. ,vol. 42, pp. 4493- 4499 ,(2001) , 10.1016/S0032-3861(00)00801-6
W LIU, S HOA, M PUGH, Fracture toughness and water uptake of high-performance epoxy/nanoclay nanocomposites Composites Science and Technology. ,vol. 65, pp. 2364- 2373 ,(2005) , 10.1016/J.COMPSCITECH.2005.06.007