Thermodynamics analysis of carbothermal-chlorination reduction in aluminum production
作者： Weijuan Yang , Xiaowei Liu , Jianzhong Liu , Zhihua Wang , Junhu Zhou
DOI: 10.1016/J.APPLTHERMALENG.2016.09.156
关键词:
摘要: Abstract Carbo-thermal reduction aluminum is regarded as the future production method for its low energy consumption. A thermodynamics analysis performed, taking Al–C two-step model objective. High temperature beneficial to reaction efficiency, but harmful exergy efficiency of first (Al2O3 + 3C + AlCl3 = 3AlCl + 3CO, R1). The second (3AlCl = AlCl3 + 2Al, R2) presents an opposite pattern. An optimal window exists AlCl mediated carbon method. R1 above 1520 K and that R2 398–798 K in window. Heat recovery significantly important enhancing both and consumption actual processes. Energy reduced from 11,335 kW h/t(Al) 8063 kW h/t(Al) when ideal heat performed. Compared with electrolytic aluminum, carbothermol-chlorination a better performance some condition. 10,151 and 13,200 kW h/t(Al) respectively. Moreover, 67% greater by 1.7 times than that aluminum.
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Ahmet Güner, Mustafa Arıkan, Mehmet Nebioglu, New Approaches to Aluminum Integral Foam Production with Casting Methods Metals. ,vol. 5, pp. 1553- 1565 ,(2015) , 10.3390/MET5031553
Harald U Sverdrup, Kristin Vala Ragnarsdottir, Deniz Koca, None, Aluminium for the future: Modelling the global production, market supply, demand, price and long term development of the global reserves Resources Conservation and Recycling. ,vol. 103, pp. 139- 154 ,(2015) , 10.1016/J.RESCONREC.2015.06.008
Fan Liu, Yida Deng, Xiaopeng Han, Wenbin Hu, Cheng Zhong, Electrodeposition of metals and alloys from ionic liquids Journal of Alloys and Compounds. ,vol. 654, pp. 163- 170 ,(2016) , 10.1016/J.JALLCOM.2015.09.137
Luis Acevedo, Sergio Usón, Javier Uche, Exergy transfer analysis of an aluminum holding furnace Energy Conversion and Management. ,vol. 89, pp. 484- 496 ,(2015) , 10.1016/J.ENCONMAN.2014.10.021
Wenzhan Yu, Bin Yang, Fulong Zhu, Wenlong Jiang, Qinchun Yu, Baoqiang Xu, Investigation of chlorination process in aluminum production by carbothermic-chlorination reduction of Al2O3 under vacuum Vacuum. ,vol. 86, pp. 1113- 1117 ,(2012) , 10.1016/J.VACUUM.2011.10.014
P.K Panda, L Mariappan, T.S Kannan, Carbothermal reduction of kaolinite under nitrogen atmosphere Ceramics International. ,vol. 26, pp. 455- 461 ,(2000) , 10.1016/S0272-8842(99)00068-1
M. Gümüş, M. Atmaca, Energy and Exergy Analyses Applied to a CI Engine Fueled with Diesel and Natural Gas Energy Sources Part A-recovery Utilization and Environmental Effects. ,vol. 35, pp. 1017- 1027 ,(2013) , 10.1080/15567036.2010.516312
M. Atmaca, Efficiency Analysis of Combined Cogeneration Systems with Steam and Gas Turbines Energy Sources, Part A: Recovery, Utilization, and Environmental Effects. ,vol. 33, pp. 360- 369 ,(2010) , 10.1080/15567031003741434
Seiichi Ujiie, Satoru Hirose, Masao Fujishige, Harumi Yokokawa, Masayuki Dokiya, Reduction Behavior of Alumina in Pure Oxygen Blast Furnace for Aluminum Production Materials Transactions Jim. ,vol. 29, pp. 589- 597 ,(1988) , 10.2320/MATERTRANS1960.29.589
Katerina Kermeli, Peter-Hans ter Weer, Wina Crijns-Graus, Ernst Worrell, Energy efficiency improvement and GHG abatement in the global production of primary aluminium Energy Efficiency. ,vol. 8, pp. 629- 666 ,(2015) , 10.1007/S12053-014-9301-7