Point defects in Cu2ZnSnSe4 (CZTSe): Resonant X‐ray diffraction study of the low‐temperature order/disorder transition
作者： L. T. Schelhas , K. H. Stone , S. P. Harvey , D. Zakhidov , A. Salleo
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摘要: The interest in Cu2ZnSn(S,Se)4 (CZTS) for photovoltaic applications is motivated by similarities to Cu(In,Ga)Se2 while being comprised of non-toxic and earth abundant elements. However, CZTS suffers from a Voc deficit, where the much lower than expected based on band gap, which may be result high concentration point-defects lattice. Recently, reports have observed low-temperature order/disorder transition Raman optical spectroscopies films reported describe ordering Cu Zn atoms crystal structure. To directly determine level Cu/Zn ordering, we used resonant-XRD, site, element specific probe long range order. We CZTSe annealed just below quenched above temperature; previous work, should ordered highly disordered, respectively. Our data show that there some near low temperature but significantly less chemical order Raman. understand both our resonant-XRD results results, present structural model involves antiphase domain boundaries accommodates excess within
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sci-hub.se 参考文章(28)
D. R. Kammler, T. O. Mason, D. L. Young, T. J. Coutts, D. Ko, K. R. Poeppelmeier, D. L. Williamson, Comparison of thin film and bulk forms of the transparent conducting oxide solution Cd1+xIn2−2xSnxO4 Journal of Applied Physics. ,vol. 90, pp. 5979- 5985 ,(2001) , 10.1063/1.1410882
M.D.S. Lekgoathi, L.D. Kock, Effect of short and long range order on crystal structure interpretation: Raman and powder X-ray diffraction of LiPF6 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 153, pp. 651- 654 ,(2016) , 10.1016/J.SAA.2015.09.025
Léo Choubrac, Alain Lafond, Michaël Paris, Catherine Guillot-Deudon, Stéphane Jobic, The stability domain of the selenide kesterite photovoltaic materials and NMR investigation of the Cu/Zn disorder in Cu2ZnSnSe4 (CZTSe). Physical Chemistry Chemical Physics. ,vol. 17, pp. 15088- 15092 ,(2015) , 10.1039/C5CP01709B
G. Rey, A. Redinger, J. Sendler, T. P. Weiss, M. Thevenin, M. Guennou, B. El Adib, S. Siebentritt, The band gap of Cu2ZnSnSe4: Effect of order-disorder Applied Physics Letters. ,vol. 105, pp. 112106- ,(2014) , 10.1063/1.4896315
Wei Wang, Mark T. Winkler, Oki Gunawan, Tayfun Gokmen, Teodor K. Todorov, Yu Zhu, David B. Mitzi, Device Characteristics of CZTSSe Thin‐Film Solar Cells with 12.6% Efficiency Advanced Energy Materials. ,vol. 4, pp. 1301465- ,(2014) , 10.1002/AENM.201301465
I.L. Repins, J.V. Li, A. Kanevce, C.L. Perkins, K.X. Steirer, J. Pankow, G. Teeter, D. Kuciauskas, C. Beall, C. Dehart, J. Carapella, B. Bob, J.-S. Park, S.-H. Wei, Effects of deposition termination on Cu2ZnSnSe4 device characteristics Thin Solid Films. ,vol. 582, pp. 184- 187 ,(2015) , 10.1016/J.TSF.2014.09.028
Susan Schorr, The crystal structure of kesterite type compounds: A neutron and X-ray diffraction study Solar Energy Materials and Solar Cells. ,vol. 95, pp. 1482- 1488 ,(2011) , 10.1016/J.SOLMAT.2011.01.002
Dominique Massiot, Robert J. Messinger, Sylvian Cadars, MichaËl Deschamps, Valerie Montouillout, Nadia Pellerin, Emmanuel Veron, Mathieu Allix, Pierre Florian, Franck Fayon, Topological, geometric, and chemical order in materials: insights from solid-state NMR. Accounts of Chemical Research. ,vol. 46, pp. 1975- 1984 ,(2013) , 10.1021/AR3003255
Ingrid Repins, Carolyn Beall, Nirav Vora, Clay DeHart, Darius Kuciauskas, Pat Dippo, Bobby To, Jonathan Mann, Wan-Ching Hsu, Alan Goodrich, Rommel Noufi, Co-evaporated Cu2ZnSnSe4 films and devices Solar Energy Materials and Solar Cells. ,vol. 101, pp. 154- 159 ,(2012) , 10.1016/J.SOLMAT.2012.01.008
Min Yan, V. Vitek, Atomistic studies of the structure and composition of grain boundaries in Cu 3 Au and Ni 3 Al Interface Science. ,vol. 3, pp. 17- 39 ,(1995) , 10.1007/BF00203981