Preparation, characterization and reactivity of a series of diethylenetriamine (dien) and substituted dien complexes of platinum(II)
作者： G. Mahal , R. Van Eldik
DOI: 10.1016/S0020-1693(00)82121-0
关键词:
摘要: Abstract The preparation and characterization of chloro, aquo hydroxo complexes diethylenetriamine (dien) methyl ethyl substituted dien Pt(II) species are reported. Evidence for the isolation ring-opened from acidic medium is presented, difficulties in isolating pure discussed. possibility producing carbonato via CO2 uptake by species, or anation bicarbonate was investigated. No evidence formation a complex type Pt(R5dien)OCO2 could be found. These results discussed reference to similar work performed on corresponding Pd(II) nature metal-hydroxy bond.
elsevier.com
sci-hub.se 参考文章(9)
G. Mahal, R. Van Eldik, Kinetics and mechanism of the formation, aquation, and base hydrolysis reactions of a series of monodentate carbonato complexes of palladium(II) Inorganic Chemistry. ,vol. 24, pp. 4165- 4170 ,(1985) , 10.1021/IC00218A037
George W. Watt, Willis A. Cude, Diethylenetriamine complexes of platinum(II) halides Inorganic Chemistry. ,vol. 7, pp. 335- 338 ,(1968) , 10.1021/IC50060A034
E.L.J. Breet, R. Van Eldik, H. Kelm, Kinetics and mechanism of some fast anation reactions of a series of substituted dien complexes of palladium(II). pH dependency in neutral and basic aqueous solutions Inorganica Chimica Acta. ,vol. 85, pp. 151- 154 ,(1984) , 10.1016/S0020-1693(00)80993-7
E. L. J. Breet, R. Van Eldik, Kinetics and mechanism of some fast substitution reactions of a series of methyl-substituted dien complexes of palladium(II) in aqueous solution Inorganic Chemistry. ,vol. 23, pp. 1865- 1869 ,(1984) , 10.1021/IC00181A017
D.A. Palmer, H. Kelm, Effect of pressure on the substitution reactions of [Pt(dien)X]+ complexes in aqueous solution Inorganica Chimica Acta. ,vol. 19, pp. 117- 128 ,(1976) , 10.1016/S0020-1693(00)91083-1
E.L.J. Breet, R. van Eldik, H. Kelm, Kinetics and mechanism of some fast anation reactions of a series of substituted dien complexes of palladium(II). Temperature and pressure dependencies in weakly acidic aqueous solution1 Polyhedron. ,vol. 2, pp. 1181- 1187 ,(1983) , 10.1016/S0277-5387(00)84354-5
Fred Basolo, Harry B. Gray, Ralph G. Pearson, Mechanism of Substitution Reactions of Complex Ions. XVII.1 Rates of Reaction of Some Platinum(II) and Palladium(II) Complexes with Pyridine2 Journal of the American Chemical Society. ,vol. 82, pp. 4200- 4203 ,(1960) , 10.1021/JA01501A021
Donald A. Palmer, Rudi Van Eldik, THE CHEMISTRY OF METAL CARBONATO AND CARBON DIOXIDE COMPLEXES ChemInform. ,vol. 15, pp. 651- 731 ,(1983) , 10.1021/CR00058A004
E.L.J. Breet, R. Van Eldik, The isolation and identification of an unusual palladium(II) substituted dien complex [1] Inorganica Chimica Acta. ,vol. 76, ,(1983) , 10.1016/S0020-1693(00)81546-7