Kinetics and mechanism of some fast anation reactions of a series of substituted dien complexes of palladium(II). pH dependency in neutral and basic aqueous solutions
作者： E.L.J. Breet , R. Van Eldik , H. Kelm
DOI: 10.1016/S0020-1693(00)80993-7
关键词: Kinetics 、 Inorganic chemistry 、 Basic solution 、 Aqueous solution 、 Iodide 、 Palladium 、 Chemistry 、 Diamine 、 Ph dependency 、 Medicinal chemistry
摘要: Abstract The anation kinetics of a series methyl and ethyl substituted dien aquo complexes palladium(II) by iodide were studied at 5 9 are ascribed to secondary reactions involving the hydroxo and/or some conjugate-base species.
elsevier.com
sci-hub.se 参考文章(3)
D.A. Palmer, R. Schmidt, R. van Eldik, H. Kelm, Temperature and pressure dependencies of the anation of Pd(MeEt4dien)OH2+2 by chloride ion in acidic aqueous solution. A mixing system for studying the kinetics of moderately fast reactions under pressure Inorganica Chimica Acta. ,vol. 29, pp. 261- 265 ,(1978) , 10.1016/S0020-1693(00)89658-9
E.L.J. Breet, R. van Eldik, H. Kelm, Kinetics and mechanism of some fast anation reactions of a series of substituted dien complexes of palladium(II). Temperature and pressure dependencies in weakly acidic aqueous solution1 Polyhedron. ,vol. 2, pp. 1181- 1187 ,(1983) , 10.1016/S0277-5387(00)84354-5
R. Van Eldik, D.A. Palmer, R. Schmidt, H. Kelm, Volumes of activation for the anation of Pd(II) substituted dien complexes by chloride ion in aqueous solution. A high pressure stopped-flow instrument for studying the kinetics of fast reactions under pressure Inorganica Chimica Acta. ,vol. 50, pp. 131- 135 ,(1981) , 10.1016/S0020-1693(00)83732-9