Hierarchically porous sulfur-containing activated carbon monoliths via ice-templating and one-step pyrolysis
作者： Aled D. Roberts , Xu Li , Haifei Zhang
DOI: 10.1016/J.CARBON.2015.08.004
关键词:
摘要: Abstract Hierarchically porous sulfur-containing activated carbons were prepared by ice-templating from an aqueous sodium poly(4-styrenesulfonate) (Na-PSS) solution followed a single 800 °C pyrolysis step. This thermal treatment induced crosslinking, with the in-situ generation of Na2SO4 (activating agent), before carbonization and activation. The also resulted in formation sulfur salts, which could be converted to elemental upon simple HCl acid wash. content monoliths measured microanalysis increased 17.07 wt. % 39.74 wt. incorporating additional into prior pyrolysis. was uniformly dispersed within micropores carbon, selectively removed degassing (heating under vacuum) at different temperatures, revealing specific surface areas up 1051 m2 g−1. materials characterized various techniques evaluated for their potential as cathode lithium–sulfur battery. work may open new facile routes prepare applications where its presence is beneficial.
core.ac.uk
cyberleninka.org
elsevier.com
sci-hub.se 参考文章(64)
Hui Zhong, Fei Xu, Zenghui Li, Ruowen Fu, Dingcai Wu, High-energy supercapacitors based on hierarchical porous carbon with an ultrahigh ion-accessible surface area in ionic liquid electrolytes Nanoscale. ,vol. 5, pp. 4678- 4682 ,(2013) , 10.1039/C3NR00738C
Dhanya Puthusseri, Vanchiappan Aravindan, Srinivasan Madhavi, Satishchandra Ogale, 3D micro-porous conducting carbon beehive by single step polymer carbonization for high performance supercapacitors: the magic of in situ porogen formation Energy and Environmental Science. ,vol. 7, pp. 728- 735 ,(2014) , 10.1039/C3EE42551G
Gabriele Centi, Siglinda Perathoner, The Role of Nanostructure in Improving the Performance of Electrodes for Energy Storage and Conversion European Journal of Inorganic Chemistry. ,vol. 2009, pp. 3851- 3878 ,(2009) , 10.1002/EJIC.200900275
Cathie Vix-Guterl, Elzbieta Frackowiak, Krzysztof Jurewicz, Marcin Friebe, Julien Parmentier, François Béguin, Electrochemical energy storage in ordered porous carbon materials Carbon. ,vol. 43, pp. 1293- 1302 ,(2005) , 10.1016/J.CARBON.2004.12.028
Darren A. Baker, Nidia C. Gallego, Frederick S. Baker, On the characterization and spinning of an organic‐purified lignin toward the manufacture of low‐cost carbon fiber Journal of Applied Polymer Science. ,vol. 124, pp. 227- 234 ,(2012) , 10.1002/APP.33596
Aled D. Roberts, Suxi Wang, Xu Li, Haifei Zhang, Hierarchical porous nitrogen-rich carbon monoliths via ice-templating: high capacity and high-rate performance as lithium-ion battery anode materials Journal of Materials Chemistry. ,vol. 2, pp. 17787- 17796 ,(2014) , 10.1039/C4TA02839B
Eduardo Humeres, Maria da Gloria B Peruch, Regina FPM Moreira, Wido Schreiner, None, Reactive intermediates of the reduction of SO2 on activated carbon Journal of Physical Organic Chemistry. ,vol. 16, pp. 824- 830 ,(2003) , 10.1002/POC.673
Haifei Zhang, Irshad Hussain, Mathias Brust, Michael F. Butler, Steven P. Rannard, Andrew I. Cooper, Aligned two- and three-dimensional structures by directional freezing of polymers and nanoparticles Nature Materials. ,vol. 4, pp. 787- 793 ,(2005) , 10.1038/NMAT1487
M.S.A. Rahaman, A.F. Ismail, A. Mustafa, A review of heat treatment on polyacrylonitrile fiber Polymer Degradation and Stability. ,vol. 92, pp. 1421- 1432 ,(2007) , 10.1016/J.POLYMDEGRADSTAB.2007.03.023
D. Lichtman, J.H. Craig, V. Sailer, M. Drinkwine, AES and XPS spectra of sulfur in sulfur compounds Applications of Surface Science. ,vol. 7, pp. 325- 331 ,(1981) , 10.1016/0378-5963(81)90080-5