Prediction of a predissociation in the A 2Σ + of HCl+ and DCl+
作者： J Raftery , W G Richards
DOI: 10.1088/0022-3700/6/7/024
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摘要: Self-consistent field calculations have been made of the potential energy curves for three states HCl+, using a basis set believed to give energies very close Hartree- Fock limit. The curve 4 Pi state, dissociating H(2S) and Cl+(3P), crosses that A2 Sigma + state. Since these may interact by spin-orbit coupling, predissociation occur in Calculations magnitude this effect both HCl+ DCl+ gives results compatible with observed emission photoelectron spectra.
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