作者: Tingting Guo , Tingting Tan , Li Duan , Zhihui Zhang
DOI: 10.1007/S10854-018-0310-8
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摘要: The switching characteristics of rare element Ce-doped HfOx films were investigated. effect Ce doping on oxygen defects was analyzed by X-ray photoelectron spectroscopy (XPS) and first-principle calculations. variations valence state vacancies with the increase concentration demonstrated. Although increased dopants-induced in film, density decreased as increased. Besides, introduction dopants enlarged difference electronegativity Hf O which made it harder for to escape from film under voltage. Hence behaviors affected multiple factors can be effectively improved an appropriate (4.3%). A physical model based formation rupture conductive filaments proposed clarify behavior samples.