Effect of rare element Ce doping concentration on resistive switching of HfOx film

作者: Tingting Guo , Tingting Tan , Li Duan , Zhihui Zhang

DOI: 10.1007/S10854-018-0310-8

关键词:

摘要: The switching characteristics of rare element Ce-doped HfOx films were investigated. effect Ce doping on oxygen defects was analyzed by X-ray photoelectron spectroscopy (XPS) and first-principle calculations. variations valence state vacancies with the increase concentration demonstrated. Although increased dopants-induced in film, density decreased as increased. Besides, introduction dopants enlarged difference electronegativity Hf O which made it harder for to escape from film under voltage. Hence behaviors affected multiple factors can be effectively improved an appropriate (4.3%). A physical model based formation rupture conductive filaments proposed clarify behavior samples.

参考文章(26)
Jung Ho Yoon, Kyung Min Kim, Seul Ji Song, Jun Yeong Seok, Kyung Jean Yoon, Dae Eun Kwon, Tae Hyung Park, Young Jae Kwon, Xinglong Shao, Cheol Seong Hwang, Pt/Ta2O5/HfO2−x/Ti Resistive Switching Memory Competing with Multilevel NAND Flash Advanced Materials. ,vol. 27, pp. 3811- 3816 ,(2015) , 10.1002/ADMA.201501167
A. Harada, H. Yamaoka, R. Ogata, K. Watanabe, K. Kinoshita, S. Kishida, T. Nokami, T. Itoh, Enhanced stability of the HfO2 electrolyte and reduced working voltage of a CB-RAM by an ionic liquid Journal of Materials Chemistry C. ,vol. 3, pp. 6966- 6969 ,(2015) , 10.1039/C5TC01127B
Jungho Shin, Insung Kim, Kuyyadi P. Biju, Minseok Jo, Jubong Park, Joonmyoung Lee, Seungjae Jung, Wootae Lee, Seonghyun Kim, Sangsu Park, Hyunsang Hwang, TiO2-based metal-insulator-metal selection device for bipolar resistive random access memory cross-point application Journal of Applied Physics. ,vol. 109, pp. 033712- ,(2011) , 10.1063/1.3544205
John P. Perdew, Kieron Burke, Matthias Ernzerhof, Generalized Gradient Approximation Made Simple Physical Review Letters. ,vol. 77, pp. 3865- 3868 ,(1996) , 10.1103/PHYSREVLETT.77.3865
Woo-Hee Kim, Min-Kyu Kim, Il-Kwon Oh, Wan Joo Maeng, Taehoon Cheon, Soo-Hyun Kim, Atif Noori, David Thompson, Schubert Chu, Hyungjun Kim, Significant Enhancement of the Dielectric Constant through the Doping of CeO2 into HfO2 by Atomic Layer Deposition Journal of the American Ceramic Society. ,vol. 97, pp. 1164- 1169 ,(2014) , 10.1111/JACE.12762
C. Dou, K. Kakushima, P. Ahmet, K. Tsutsui, A. Nishiyama, N. Sugii, K. Natori, T. Hattori, H. Iwai, Resistive switching behavior of a CeO 2 based ReRAM cell incorporated with Si buffer layer Microelectronics Reliability. ,vol. 52, pp. 688- 691 ,(2012) , 10.1016/J.MICROREL.2011.10.019
Myung Soo Lee, Sungho Choi, Chee-Hong An, Hyoungsub Kim, Resistive switching characteristics of solution-deposited Gd, Dy, and Ce-doped ZrO2 films Applied Physics Letters. ,vol. 100, pp. 143504- ,(2012) , 10.1063/1.3700728
Mei Ji, Lei Wang, Feng Wei, Hailing Tu, Jun Du, Study of negative oxygen vacancies in Gd2O3-doped HfO2 thin films as high-k gate dielectrics Semiconductor Science and Technology. ,vol. 25, pp. 075008- ,(2010) , 10.1088/0268-1242/25/7/075008
Limei Qiu, Fen Liu, Liangzhong Zhao, Ying Ma, Jiannian Yao, Comparative XPS study of surface reduction for nanocrystalline and microcrystalline ceria powder Applied Surface Science. ,vol. 252, pp. 4931- 4935 ,(2006) , 10.1016/J.APSUSC.2005.07.024