Enhanced Dielectric Response in Mg-doped CaCu3Ti4O12 Ceramics

作者: Wang Li , Shenyu Qiu , Nan Chen , Guoping Du

DOI: 10.1016/S1005-0302(10)60107-7

关键词:

摘要: CaCu 3 Ti 4 O 12 ceramics substituted by Mg for Ca were prepared the solid state reaction method. The crystal structures, microstructures, and dielectric properties of 1- x Cu investigated. At lower doping concentrations, substitution caused a decreased lattice constant, while at higher some dopants started to replace resulted in an increased could also due similar ion radius between ions. was found promote grain growth during sintering. Grain boundary resistance be doping. Enhanced observed with =0.05 frequency range from 1 kHz 20 kHz. For other losses generally lowered.

参考文章(22)
Eric A. Patterson, Seunghwa Kwon, Chien-Chih Huang, David P. Cann, Effects of ZrO2 additions on the dielectric properties of CaCu3Ti4O12 Applied Physics Letters. ,vol. 87, pp. 182911- ,(2005) , 10.1063/1.2126142
Yueyue Yan, Lei Jin, Lixin Feng, Guanghan Cao, Decrease of dielectric loss in giant dielectric constant CaCu3 Ti4 O12 ceramics by adding CaTiO3 Materials Science and Engineering B-advanced Functional Solid-state Materials. ,vol. 130, pp. 146- 150 ,(2006) , 10.1016/J.MSEB.2006.02.060
C. L. Chen, L. Chen, R. P. Bontchev, A. Jacobson, J. C. Jiang, E. I. Meletis, J. Horwitz, H.-D. Wu, Y. Lin, Y. B. Chen, T. Garret, S. W. Liu, Epitaxial growth of dielectric CaCu3Ti4O12 thin films on (001) LaAlO3 by pulsed laser deposition Applied Physics Letters. ,vol. 81, pp. 631- 633 ,(2002) , 10.1063/1.1490624
M. Li, Gemei Cai, D. F. Zhang, W. Y. Wang, W. J. Wang, X. L. Chen, Enhanced dielectric responses in Mg-doped CaCu3Ti4O12 Journal of Applied Physics. ,vol. 104, pp. 074107- ,(2008) , 10.1063/1.2989124
Ming Li, Antonio Feteira, Derek C. Sinclair, Anthony R. West, Influence of Mn doping on the semiconducting properties of CaCu3Ti4O12 ceramics Applied Physics Letters. ,vol. 88, pp. 232903- ,(2006) , 10.1063/1.2200732
Seong-Hyeon Hong, Doh-Yeon Kim, Hyun-Min Park, Young-Min Kim, Electric and Dielectric Properties of Nb‐Doped CaCu3Ti4O12 Ceramics Journal of the American Ceramic Society. ,vol. 90, pp. 2118- 2121 ,(2007) , 10.1111/J.1551-2916.2007.01709.X
Shuhua Jin, Haiping Xia, Yuepin Zhang, Effect of La-doping on the properties of CaCu3Ti4O12 dielectric ceramics Ceramics International. ,vol. 35, pp. 309- 313 ,(2009) , 10.1016/J.CERAMINT.2007.10.007
Kang-Min Kim, Sun-Jung Kim, Jong-Heun Lee, Doh-Yeon Kim, Microstructural evolution and dielectric properties of SiO2-doped CaCu3Ti4O12 ceramics Journal of The European Ceramic Society. ,vol. 27, pp. 3991- 3995 ,(2007) , 10.1016/J.JEURCERAMSOC.2007.02.081
R. D. Shannon, C. T. Prewitt, Effective ionic radii in oxides and fluorides Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. ,vol. 25, pp. 925- 946 ,(1969) , 10.1107/S0567740869003220
Guoping Du, Wang Li, Yao Fu, Nan Chen, Chuanqiang Yin, Mingming Yan, An investigation on the solid-state reactions in CaCu3Ti4O12-ZnNb2O6 system Materials Research Bulletin. ,vol. 43, pp. 2504- 2508 ,(2008) , 10.1016/J.MATERRESBULL.2007.08.018