Studies of ABS-graft-maleic anhydride/clay nanocomposites: Morphologies, thermal stability and flammability properties

作者: Haiyun Ma , Zhongbin Xu , Lifang Tong , Aiguan Gu , Zhengping Fang

DOI: 10.1016/J.POLYMDEGRADSTAB.2006.08.017

关键词:

摘要: Abstract ABS- g -MAH (maleic anhydride) with different grafting degree, ABS/OMT (organo montmorillonite) and -MAH/OMT nanocomposites were prepared via melt blending. The reaction, phase morphology, clay dispersion, thermal properties, dynamic mechanical properties flammability investigated. FTIR spectra results indicate that maleic anhydride was successfully grafted onto butadiene chains of the ABS backbone in molten state using dicumyl peroxide as initiator styrene comonomer relative degree increased increasing loading MAH. TEM images show size dispersed rubber domains dispersion is more uniform than neat resin. XRD intercalated/exfoliated structure formed intercalated into layers distributed both SAN phase. TGA reveal has better barrier stability ones nanocomposites. T also higher cone measurements exhibit significantly reduced when compared to even at same content. chars tighter, denser, integrated fewer surface microcracks residues.

参考文章(24)
Shaofeng Wang, Yuan Hu, Ruowen Zong, Yong Tang, Zuyao Chen, Weicheng Fan, Preparation and characterization of flame retardant ABS/montmorillonite nanocomposite Applied Clay Science. ,vol. 25, pp. 49- 55 ,(2004) , 10.1016/J.CLAY.2003.08.003
S SU, Polybutadiene-modified clay and its nanocomposites Polymer Degradation and Stability. ,vol. 84, pp. 279- 288 ,(2004) , 10.1016/J.POLYMDEGRADSTAB.2003.09.023
Jin Zhu, Alexander B. Morgan, Frank J. Lamelas, Charles A. Wilkie, Fire Properties of Polystyrene-Clay Nanocomposites Chemistry of Materials. ,vol. 13, pp. 3774- 3780 ,(2001) , 10.1021/CM000984R
R. K. Bharadwaj, MODELING THE BARRIER PROPERTIES OF POLYMER-LAYERED SILICATE NANOCOMPOSITES Macromolecules. ,vol. 34, pp. 9189- 9192 ,(2001) , 10.1021/MA010780B
S Balakrishnan, N.R Neelakantan, D.Nabi Saheb, Jyoti P Jog, Rheological and morphological behaviour of blends of polycarbonate with unmodified and maleic anhydride grafted ABS Polymer. ,vol. 39, pp. 5765- 5771 ,(1998) , 10.1016/S0032-3861(98)00088-3
Florêncio G Ramos Filho, Tomás Jeferson A Mélo, Marcelo S Rabello, Suédina ML Silva, None, Thermal stability of nanocomposites based on polypropylene and bentonite Polymer Degradation and Stability. ,vol. 89, pp. 383- 392 ,(2005) , 10.1016/J.POLYMDEGRADSTAB.2004.12.011
D. Shah, P. Maiti, D. D. Jiang, C. A. Batt, E. P. Giannelis, Effect of Nanoparticle Mobility on Toughness of Polymer Nanocomposites Advanced Materials. ,vol. 17, pp. 525- 528 ,(2005) , 10.1002/ADMA.200400984