Electrochemical and atomic force microscopy investigations of new materials from N-trifluoromethanesulfonyl-1-azahexa-1,3,5-trienes derivatives

作者: Margarita Rivera , Cecilio Alvarez-Toledano , Abel Moreno , José D. Sepúlveda-Sánchez , Tomás Hernández-Pérez

DOI: 10.1590/S0103-50532005000300004

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摘要: Thin films have been created on the surface of highly oriented pyrolytic graphite electrodes from chemically synthesized p-donor species by using cyclic voltammetry technique and in situ electrochemistry-atomic force microscopy. Results indicate that it is possible to form new compounds called molecular materials coupling electro-oxidized N-trifluoromethanesulfonyl-1-azahexa-1,3,5-triene a [Cr(C2O4)3]3- anion. Different techniques such as AFM, SEM EDS were employed characterize morphology composition. exhibited particular electrochemical response different film texture depending chemical composition starting compounds.

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