Luminescence properties of Mn5+ in a variety of host lattices: Effects of chemical and structural variation
作者： Ueli Oetliker , Markus Herren , Hans U. Güdel , Ute Kesper , Christa Albrecht
DOI: 10.1063/1.466720
关键词:
摘要: The optical spectroscopic properties of Mn5+ doped into ten host lattices have been studied. influence both chemical variation [phosphates(V), arsenates(V), and vanadates(V)] structural (spodiosites, apatites, Li3PO4‐type salts) on the luminescence is studied in detail. By varying lattice, position sharp band can be varied from 8300 to 8960 cm−1. Excited state splittings, lifetimes, sideband intensities are correlated with geometrical distortion MnO3−4 tetrahedron. In all lattices, originates 1E excited at temperatures. It essentially unquenched room temperature apatite whereas spodiosites up 90% may quenched temperature.
scitation.org
harvard.edu
aip.org
sci-hub.se 参考文章(14)
J. S. Griffith, The Theory of Transition-Metal Ions ,(1961)
J. D. Kingsley, J. S. Prener, B. Segall, Spectroscopy of MnO43−in Calcium Halophosphates Physical Review. ,vol. 137, pp. A189- A202 ,(1965) , 10.1103/PHYSREV.137.A189
Andrew D. Liehr, RECIPROCATION OF ELECTROSTATIC AND ELECTROMAGNETIC FORCES IN LIGAND FIELD THEORY1,2 The Journal of Physical Chemistry. ,vol. 64, pp. 43- 51 ,(1960) , 10.1021/J100830A011
Stuart M. Jacobsen, Hans U. Guedel, Claude A. Daul, Excited states of titanium(2+): sharp-band and broad-band near-infrared luminescence from titanium(2+) in magnesium chloride and magnesium bromide Journal of the American Chemical Society. ,vol. 110, pp. 7610- 7616 ,(1988) , 10.1021/JA00231A005
Larry D. Merkle, Albert Pinto, Horacio R. Verdún, Bruce McIntosh, Laser action from Mn5+ in Ba3(VO4)2 Applied Physics Letters. ,vol. 61, pp. 2386- 2388 ,(1992) , 10.1063/1.108172
Renato Borromei, Luigi Oleari, Peter Day, Electronic spectrum of the manganate(V) ion in different host lattices Journal of the Chemical Society, Faraday Transactions. ,vol. 77, pp. 1563- 1578 ,(1981) , 10.1039/F29817701563
J. B. Milstein, J. Ackerman, S. L. Holt, B. R. McGarvey, Electronic structures of chromium(V) and manganese(V) in phosphate and vanadate hosts Inorganic Chemistry. ,vol. 11, pp. 1178- 1184 ,(1972) , 10.1021/IC50112A004
P.F. Moulton, Tunable solid-state lasers Proceedings of the IEEE. ,vol. 80, pp. 348- 364 ,(1992) , 10.1109/5.135352
J.A. Capobianco, G. Cormier, M. Bettinelli, R. Moncorgé, H. Manaa, Near-infrared intraconfigurational luminescence spectroscopy of the Mn5+ (3d2) ion in Ca2PO4Cl, Sr5(PO4)3Cl, Ca2VO4Cl and Sr2VO4Cl Journal of Luminescence. ,vol. 54, pp. 1- 11 ,(1992) , 10.1016/0022-2313(92)90043-9
K.R. Hoffman, U. Hömmerich, S.M. Jacobsen, W.M. Yen, On the emission and excitation spectrum of the NIR laser center in Cr:YAG Journal of Luminescence. ,vol. 52, pp. 277- 279 ,(1992) , 10.1016/0022-2313(92)90031-4