Electropolymerization of palladium tetraaminephthalocyanine: Characterization and supercapacitance behavior

作者: Koodlur Sannegowda Lokesh , Annemie Adriaens

DOI: 10.1016/J.DYEPIG.2014.06.034

关键词:

摘要: Abstract The formation of a supramolecular electropolymerized film polymeric palladium phthalocyanine on glassy carbon electrode is reported here. was obtained by cycling monomeric tetraaminephthalocyanine in dimethyl sulfoxide the potential range −0.5 to +1.0 V. functionalized polymerized characterized using Raman spectroscopy, X-ray photoelectron spectroscopy and electrochemical methods. A shown to form oxidation peripheral amino groups. It uniformly completely covered surface. modified surface slightly blocked reversible redox behavior probe owing thick its showed capacitance 146 F g −1 at 0.27 V 0.5 M sulfuric acid.

参考文章(40)
C. C. Leznoff, A. B. P. Lever, Phthalocyanines : properties and applications Wiley. ,(1989)
A. Sheila Holmes-Smith, Alan Hamill, Michael Campbell, Mahesh Uttamlal, Electropolymerised platinum porphyrin polymers for dissolved oxygen sensing Analyst. ,vol. 124, pp. 1463- 1466 ,(1999) , 10.1039/A904634H
Paul A. Liddell, Miguel Gervaldo, James W. Bridgewater, Amy E. Keirstead, Su Lin, Thomas A. Moore, Ana L. Moore, Devens Gust, Porphyrin-Based Hole Conducting Electropolymer Chemistry of Materials. ,vol. 20, pp. 135- 142 ,(2008) , 10.1021/CM7022955
Dieter Wöhrle, Olaf Hild, Nicola Trombach, Rüdiger Benters, Günter Schnurpfeil, Olga Suvorova, Conjugated polymeric phthalocyanines by polycyclotetramerization and electropolymerization Macromolecular Symposia. ,vol. 186, pp. 99- 104 ,(2002) , 10.1002/1521-3900(200208)186:1<99::AID-MASY99>3.0.CO;2-F
A. A. McConnell, J. A. Nimmo, W. E. Smith, Surface‐enhanced resonance Raman spectroscopy of sulphonated copper phthalocyanine at a silver electrode Journal of Raman Spectroscopy. ,vol. 20, pp. 375- 380 ,(1989) , 10.1002/JRS.1250200606
Barry P. Rand, Jiangeng Xue, Fan Yang, Stephen R. Forrest, Organic solar cells with sensitivity extending into the near infrared Applied Physics Letters. ,vol. 87, pp. 233508- ,(2005) , 10.1063/1.2140075
Robert de Levie, Fractals and rough electrodes Journal of Electroanalytical Chemistry. ,vol. 281, pp. 1- 21 ,(1990) , 10.1016/0022-0728(90)87025-F
Krzysztof Bieńkowski, Marcin Strawski, Marek Szklarczyk, The determination of the thickness of electrodeposited polymeric films by AFM and electrochemical techniques Journal of Electroanalytical Chemistry. ,vol. 662, pp. 196- 203 ,(2011) , 10.1016/J.JELECHEM.2011.06.014