Electrochemical formation of Mg–Lu alloy and alloy layer in molten LiCl–KCl

作者: Tao Jiang , Ning Wang , Shu-Ming Peng , Mei Li , Wei Han

DOI: 10.1016/J.JALLCOM.2015.10.159

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摘要: Abstract In the present work, electrochemical behaviors of Lu (III) ions in molten LiCl–KCl and LiCl–KCl–MgCl 2 were investigated by cyclic voltammetry, square wave chronopotentiometry, respectively. Galvanostatic electrolysis was conducted on a molybdenum electrode to prepare Mg–Lu alloys, while potentiostatic magnesium alloy layers. The microstructure microzone analysis obtained deposits characterized XRD SEM–EDS. An intermetallic compound MgLu formed galvanostatic electrolysis, whereas two kinds (Mg 24 5 MgLu) metal layer.

参考文章(34)
Thaddeus B Massalski, Hiroaki Okamoto, PRnbsp Subramanian, Linda Kacprzak, William W Scott, None, Binary alloy phase diagrams ASM International. ,vol. 3, pp. 2874- ,(1986)
M. Gibilaro, L. Massot, P. Chamelot, P. Taxil, Study of neodymium extraction in molten fluorides by electrochemical co-reduction with aluminium Journal of Nuclear Materials. ,vol. 382, pp. 39- 45 ,(2008) , 10.1016/J.JNUCMAT.2008.09.004
Shuquan Wei, Milin Zhang, Wei Han, Yongde Yan, Yun Xue, Meng Zhang, Bin Zhang, None, Electrochemical behavior of antimony and electrodeposition of Mg–Li–Sb alloys from chloride melts Electrochimica Acta. ,vol. 56, pp. 4159- 4166 ,(2011) , 10.1016/J.ELECTACTA.2011.01.104
J. Plíva, Kinetics of electrode processes. I. Introduction Collection of Czechoslovak Chemical Communications. ,vol. 18, pp. 7- 10 ,(1953) , 10.1135/CCCC19530007
J. Serp, P. Chamelot, S. Fourcaudot, R.J.M. Konings, R. Malmbeck, C. Pernel, J.C. Poignet, J. Rebizant, J.-P. Glatz, Electrochemical behaviour of americium ions in LiCl–KCl eutectic melt Electrochimica Acta. ,vol. 51, pp. 4024- 4032 ,(2006) , 10.1016/J.ELECTACTA.2005.11.016
J Serp, R.J.M Konings, R Malmbeck, J Rebizant, C Scheppler, J.-P Glatz, Electrochemical behaviour of plutonium ion in LiCl–KCl eutectic melts Journal of Electroanalytical Chemistry. ,vol. 561, pp. 143- 148 ,(2004) , 10.1016/J.JELECHEM.2003.07.027
Yi SUN, Milin ZHANG, Wei HAN, Yongde YAN, Yusheng YANG, Yunxia SUN, Electrochemical behaviour and codeposition of Al-Li-Er alloys in LiCl-KCl-AlCl3-Er2O3 melts Journal of Rare Earths. ,vol. 31, pp. 192- 197 ,(2013) , 10.1016/S1002-0721(12)60257-9
Y. Castrillejo, M.R. Bermejo, A.I. Barrado, R. Pardo, E. Barrado, A.M. Martínez, Electrochemical behaviour of dysprosium in the eutectic LiCl–KCl at W and Al electrodes Electrochimica Acta. ,vol. 50, pp. 2047- 2057 ,(2005) , 10.1016/J.ELECTACTA.2004.09.013
J. N. Mathur, M. S. Murali, K. L. Nash, ACTINIDE PARTITIONING—A REVIEW Solvent Extraction and Ion Exchange. ,vol. 19, pp. 357- 390 ,(2001) , 10.1081/SEI-100103276