Hydrolysis of bis(dimethylamido)tin to tin (II) oxyhydroxide and its selective transformation into tin (II) or tin (IV) oxide
作者： Jayaprakash Khanderi , Lei Shi , Alexander Rothenberger
DOI: 10.1016/J.ICA.2014.11.031
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摘要: Abstract Sn 6 O 4 (OH) , a hydrolysis product of Sn(NMe 2 ) is transformed to tin (II) or (IV) oxide by solid and solution phase processing. Tin formed heating at ⩽200 °C in air under inert atmosphere. nanoparticles are the presence carboxylic acid base room temperature. IR spectroscopy, Raman thermogravimetry (coupled with infrared spectroscopy), powder X-ray diffraction, high temperature scanning electron transmission microscopy used for characterization investigation its selective decomposition into SnO . Spectroscopic diffraction results indicate that removal water from crystalline SEM shows octahedral morphology particle size 400 nm–2 μm during state conversion. Solution transformation occurs potassium glutarate oxygen. particles 15–20 nm size.
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