Atmospheric fall-out of POPs (PCDD-Fs, PCBs, HCB, PAHs) around the industrial district of Porto Marghera, Italy.

作者: Paolo Rossini , Stefano Guerzoni , Gabriele Matteucci , Massimo Gattolin , Giorgio Ferrari

DOI: 10.1016/J.SCITOTENV.2005.01.011

关键词:

摘要: In order to estimate the importance of atmospheric fall-out persistent organic pollutants (POPs) around industrial district Porto Marghera, Italy, depositions POPs were collected using bulk samplers inside Lagoon Venice. Seventy-seven deposition samples monthly over a 12-month period (March 2003-March 2004) at seven sites located close area Marghera. Samples analysed by HRGC/HRMS for PCDD-Fs, PCBs, HCB and PAHs. Differences in mean daily fluxes all between industrial, urban lagoonal stations clear, being higher than target values dioxin recommended EU strategy on dioxins, furans polychlorobiphenyls. calculate loadings district, we considered an defined distance 10 km from hypothetical centre-point main sources emissions The calculated loadings, compared with previous estimates, show that annual are 12, 510, 90 130 kg PAHs, respectively, corresponding 350-500 mg TEQ, thus indicating slight decrease PCBs great respect 1998-99. input coming atmosphere is same magnitude due watershed runoff approximately one-half direct discharges.

参考文章(22)
R Wenning, D Dodge, B Peck, K Shearer, W Luksemburg, S Della Sala, R Scazzola, Screening-level ecological risk assessment of polychlorinated dibenzo-p-dioxins and dibenzofurans in sediments and aquatic biota from the Venice Lagoon, Italy. Chemosphere. ,vol. 40, pp. 1179- 1187 ,(2000) , 10.1016/S0045-6535(99)00367-7
Raquel Duarte-Davidson, Peter Clayton, Peter Coleman, Brian J. Davis, Crispin J. Halsall, Peter Harding-Jones, Karl Pettit, Mike J. Woodfield, Kevin C. Jones, Polychlorinated dibenzo-p-dioxins (PCDDs) and furans (PCDFs) in urban air and deposition in the United Kingdom Environmental Science and Pollution Research. ,vol. 1, pp. 262- 270 ,(1994) , 10.1007/BF02986542
Jürgen Schröder, Kerstin Welsch-Pausch, Michael S McLachlan, Measurement of atmospheric deposition of polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) to a soil Atmospheric Environment. ,vol. 31, pp. 2983- 2989 ,(1997) , 10.1016/S1352-2310(97)00107-6
S. Guerzoni, P. Rossini, E. Molinaroli, G. Rampazzo, S. Raccanelli, Measurement of atmospheric deposition of polychlorinated dibenzo-p-dioxins and dibenzofurans in the Lagoon of Venice, Italy. Chemosphere. ,vol. 54, pp. 1309- 1317 ,(2004) , 10.1016/S0045-6535(03)00249-2
Michael Horstmann, Michael S. McLachlan, Sampling bulk deposition of polychlorinated dibenzo- p-dioxins and dibenzofurans Atmospheric Environment. ,vol. 31, pp. 2977- 2982 ,(1997) , 10.1016/S1352-2310(97)00106-4
Frederick W. Kutz, Donald G. Barnes, David P. Bottimore, Helmut Greim, Erich W. Bretthauer, The international toxicity equivalency factor (I-TEF) method of risk assessment for complex mixtures of dioxins and related compounds Chemosphere. ,vol. 20, pp. 751- 757 ,(1990) , 10.1016/0045-6535(90)90178-V
Emilio Benfenati, Giulio Mariani, Roberto Fanelli, Erik H. G. Evers, Elena Fattore, Patterns and sources of polychlorinated dibenzo-p-dioxins and dibenzofurans in sediments from the Venice Lagoon, Italy Environmental Science & Technology. ,vol. 31, pp. 1777- 1784 ,(1997) , 10.1021/ES9608860
Begoña Jimenez, Luis Manuel Hernandez, Maria Jose Gonzalez, Ethel Eljarrat, Josep Rivera, Maria Cristina Fossi, Congener Specific Analysis of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans in Crabs and Sediments from the Venice and Orbetello Lagoons, Italy Environmental Science & Technology. ,vol. 32, pp. 3853- 3861 ,(1998) , 10.1021/ES9801994
John G. Cole, Donald Mackay, Kevin C. Jones, Ruth E. Alcock, Interpreting, correlating, and predicting the multimedia concentrations of PCDD/Fs in the United Kingdom Environmental Science & Technology. ,vol. 33, pp. 399- 405 ,(1999) , 10.1021/ES980729W