Facile synthesis and the sensitized luminescence of europium ions-doped titanate nanowires

作者: Jianbo Yin , Xiaopeng Zhao

DOI: 10.1016/J.MATCHEMPHYS.2008.10.011

关键词:

摘要: Abstract Europium (Eu) ions-doped titanate nanowires were synthesized via a sol–gel-hydrothermal chemistry and they found to be roll multilayered trititanate-type intercalated with Eu3+ alkali ions. The average diameter was about 20 nm for in NaOH solution 10 nm KOH solution. Under ultraviolet excitation the showed bright red emission corresponding 5D0–7Fj of ions at room temperature, which attributed non-radiative energy transfer from surrounding Ti–O octahedral nanosheets central interlayer. luminescent properties influenced by type co-intercalated ions, doping degree, hydrothermal annealing temperatures. intensity ratio 5D0–7F2 5D0–7F1 Na+ higher than that K+ increased Eu3+-doping degree reached quenching level Eu/Ti = 15 mol%. efficiency temperature. However, samples high temperature led decrease emission.

参考文章(69)
A. C. Yanes, J. Del Castillo, M. Torres, J. Peraza, V. D. Rodríguez, J. Méndez-Ramos, Nanocrystal-size selective spectroscopy in SnO2:Eu3+ semiconductor quantum dots Applied Physics Letters. ,vol. 85, pp. 2343- 2345 ,(2004) , 10.1063/1.1790039
Jungsik Bang, Heesun Yang, Paul H. Holloway, Enhanced luminescence of SiO2:Eu3+ by energy transfer from ZnO nanoparticles Journal of Chemical Physics. ,vol. 123, pp. 084709- 084709 ,(2005) , 10.1063/1.2007647
S. Zhang, L.-M. Peng, Q. Chen, G. H. Du, G. Dawson, W. Z. Zhou, Formation mechanism of H2Ti3O7 nanotubes Physical Review Letters. ,vol. 91, pp. 256103- ,(2003) , 10.1103/PHYSREVLETT.91.256103
A. Conde-Gallardo, M. Garcı́a-Rocha, I. Hernández-Calderón, R. Palomino-Merino, Photoluminescence properties of the Eu3+ activator ion in the TiO2 host matrix Applied Physics Letters. ,vol. 78, pp. 3436- 3438 ,(2001) , 10.1063/1.1372338
Changfeng Wu, Weiping Qin, Guanshi Qin, Dan Zhao, Jisen Zhang, Shihua Huang, Shaozhe Lü, Huangqing Liu, Haiyan Lin, Photoluminescence from surfactant-assembled Y2O3:Eu nanotubes Applied Physics Letters. ,vol. 82, pp. 520- 522 ,(2003) , 10.1063/1.1542685
G. Wakefield, E. Holland, P. J. Dobson, J. L. Hutchison, Luminescence Properties of Nanocrystalline Y2O3:Eu Advanced Materials. ,vol. 13, pp. 1557- 1560 ,(2001) , 10.1002/1521-4095(200110)13:20<1557::AID-ADMA1557>3.0.CO;2-W
Andrea V. Firth, D. J. Cole-Hamilton, J. W. Allen, Optical properties of CdSe nanocrystals in a polymer matrix Applied Physics Letters. ,vol. 75, pp. 3120- 3122 ,(1999) , 10.1063/1.125250
Zhong-Yong Yuan, Bao-Lian Su, Titanium oxide nanotubes, nanofibers and nanowires Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 241, pp. 173- 183 ,(2004) , 10.1016/J.COLSURFA.2004.04.030
S. J. Xu, S. J. Chua, B. Liu, L. M. Gan, C. H. Chew, G. Q. Xu, Luminescence characteristics of impurities-activated ZnS nanocrystals prepared in microemulsion with hydrothermal treatment Applied Physics Letters. ,vol. 73, pp. 478- 480 ,(1998) , 10.1063/1.121906
Hongwei Song, Lixin Yu, Shaozhe Lu, Tie Wang, Zhongxin Liu, Linmei Yang, Remarkable differences in photoluminescent properties between LaPO4:Eu one-dimensional nanowires and zero-dimensional nanoparticles Applied Physics Letters. ,vol. 85, pp. 470- 472 ,(2004) , 10.1063/1.1773616