Preparation of crystalline carbon nitride films on silicon substrate by chemical vapor deposition

作者: H.K. Woo , Yafei Zhang , S.T. Lee , C.S. Lee , Y.W. Lam

DOI: 10.1016/S0925-9635(96)00615-2

关键词:

摘要: Polycrystalline carbon nitride films have been deposited on Si(111) substrates by d.c. and r.f. plasma-assisted hot filament chemical vapor deposition using a mixture of NH3, CH4 H2. For prepared b2 both methods, the X-ray diffraction peaks match those theoretical β-C3N4 structure. Raman scattering detects no diamond, graphite or amorphous in films. XPS analysis shows that contain mainly CN, CN bonding structures. The N to C concentration ratio is estimated be 0.36 0.16, respectively.

参考文章(11)
G. Beamson, D. Briggs, High resolution XPS of organic polymers The Scienta ESCA 300 Database. ,(1992)
Tyan‐Ywan Yen, Chang‐Pin Chou, Growth and characterization of carbon nitride thin films prepared by arc‐plasma jet chemical vapor deposition Applied Physics Letters. ,vol. 67, pp. 2801- 2803 ,(1995) , 10.1063/1.114789
Yafei Zhang, Zhonghua Zhou, Hulin Li, Crystalline carbon nitride films formation by chemical vapor deposition Applied Physics Letters. ,vol. 68, pp. 634- 636 ,(1996) , 10.1063/1.116492
J. Mort, M. A. Machonkin, K. Okumura, Compensation effects in nitrogen‐doped diamond thin films Applied Physics Letters. ,vol. 59, pp. 3148- 3150 ,(1991) , 10.1063/1.105767
C. Niu, Y. Z. Lu, C. M. Lieber, Experimental Realization of the Covalent Solid Carbon Nitride Science. ,vol. 261, pp. 334- 337 ,(1993) , 10.1126/SCIENCE.261.5119.334
He-Xiang Han, Bernard J. Feldman, Structural and optical properties of amorphous carbon nitride Solid State Communications. ,vol. 65, pp. 921- 923 ,(1988) , 10.1016/0038-1098(88)90732-6
A. Y. LIU, M. L. COHEN, Prediction of new low compressibility solids. Science. ,vol. 245, pp. 841- 842 ,(1989) , 10.1126/SCIENCE.245.4920.841
Kin Man Yu, Marvin L. Cohen, E. E. Haller, W. L. Hansen, Amy Y. Liu, I. C. Wu, Observation of crystalline C3N4. Physical Review B. ,vol. 49, pp. 5034- 5037 ,(1994) , 10.1103/PHYSREVB.49.5034
D. MARTON, K. J. BOYD, J. W RABALAIS, SYNTHESIS OF CARBON NITRIDE International Journal of Modern Physics B. ,vol. 09, pp. 3527- 3558 ,(1995) , 10.1142/S0217979295001385