In Situ Infrared Study of Methanol Synthesis from H2/CO over Cu/SiO2and Cu/ZrO2/SiO2

作者: Ian A. Fisher , Alexis T. Bell

DOI: 10.1006/JCAT.1998.2134

关键词:

摘要: … stepwise hydrogenation of CO to form formyl, formaldehyde, and then methoxide species, the final precursor to methanol (48). Methanol is then formed via reductive elimination of the …

参考文章(63)
I.A. Fisher, H.C. Woo, A.T. Bell, Effects of zirconia promotion on the activity of Cu/SiO2 for methanol synthesis from CO/H2 and CO2/H2 Catalysis Letters. ,vol. 44, pp. 11- 17 ,(1997) , 10.1023/A:1018916806816
Daniel Bianchi, T. Chafik, Mohamed Khalfallah, Stanislas Jean Teichner, Intermediate species on zirconia supported methanol aerogel catalysts. IV: Adsorption of carbon dioxide Applied Catalysis A-general. ,vol. 112, pp. 219- 235 ,(1994) , 10.1016/0926-860X(94)80221-1
Daniel Bianchi, Jean-Louis Gass, Mohamed Khalfallah, Stanislas Jean Teichner, Intermediate species on zirconia supported methanol aerogel catalysts: I. State of the catalyst surface before and after the adsorption of hydrogen Applied Catalysis A-general. ,vol. 101, pp. 297- 315 ,(1993) , 10.1016/0926-860X(93)80276-V
Daniel Bianchi, Tarik Chafik, Mohamed Khalfallah, Stanislas Jean Teichner, Intermediate species on zirconia supported methanol aerogel catalysts. III: Adsorption of carbon monoxide on copper containing solids Applied Catalysis A-general. ,vol. 112, pp. 57- 73 ,(1994) , 10.1016/0926-860X(94)80136-3
C. Sellmer, R. Prins, N. Kruse, XPS/SIMS studies of the promoter action in methanol synthesis over silica-supported Pd catalysts Catalysis Letters. ,vol. 47, pp. 83- 89 ,(1997) , 10.1023/A:1019000903974
N JACKSON, Methanol synthesis mechanism over zirconium dioxide Journal of Catalysis. ,vol. 101, pp. 90- 102 ,(1986) , 10.1016/0021-9517(86)90232-0
T. Chafik, D. Bianchi, S. J. Teichner, On the mechanism of the methanol synthesis involving a catalyst based on zirconia support Topics in Catalysis. ,vol. 2, pp. 103- 116 ,(1995) , 10.1007/BF01491959