Resonant X-ray emission spectroscopy reveals d-d ligand-field states involved in the self-assembly of a square-planar platinum complex
作者： Claudio Garino , Erik Gallo , Nikolay Smolentsev , Pieter Glatzel , Roberto Gobetto
DOI: 10.1039/C2CP42451G
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摘要: Resonant X-ray Emission Spectroscopy (RXES) is used to characterize the ligand field states of prototypic self-assembled square-planar complex, [Pt(tpy)Cl]Cl (tpy=2,2′:6′,2′′-terpyridine), and determine effect weak metal–metal π–π interactions on their energy.
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