Mechanism of Chemiluminescence Reaction between Hypobromite and Ammonia or Urea
作者： Xincheng Hu , Norimichi Takenaka , Masaru Kitano , Hiroshi Bandow , Yasuaki Maeda
DOI: 10.1246/BCSJ.69.1179
关键词:
摘要: The reaction kinetics, the chemiluminescence spectra, products, and lifetimes of emission species for between hypobromite ammonia or urea in an alkaline aqueous solution were investigated. Results show that mechanism is different from urea. produces NO2 gaseous phase NO2− solution; however, does not. For hypobromite, intensity obeys 1.5 order kinetics concentration when excess, but second excess. spectrum with shows a maximum at 710, 510 nm, respectively. 0.056 0.092 s ...
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