A new ring opening reaction of 2-furaldehyde diphenyl dithioacetal via reductive silylation. Preparation of 2,3,4-tris(trimethylsilyl)-3-alkenyl and 3,4,4-tris(trimethylsilyl)-2-butenyl ketones.
作者： Kunio Atsumi , Isao Kuwajima
DOI: 10.1246/CL.1978.387
关键词:
摘要: 5-Substituted 2-furaldehyde diphenyl dithioacetals are found to undergo facile ring-opening reaction and give the corresponding polysilylated ketones when they were treated with metallic sodium in presence of chlorotrimethylsilane.
csj.jp参考文章(2)
Isao Kuwajima, Kunio Atsumi, Ichiro Azegami, Reductive silylation reactions of ethyl 2-furoates Journal of the Chemical Society, Chemical Communications. pp. 76- 76 ,(1977) , 10.1039/C39770000076
Isao Kuwajima, Toru Abe, Kunio Atsumi, REDUCTIVE SILYLATION REACTIONS OF SULFIDES. A FACILE CONVERSION OF CARBON-SULFUR LINKAGES INTO CARBON-SILICON ONES Chemistry Letters. ,vol. 7, pp. 383- 386 ,(1978) , 10.1246/CL.1978.383