Chromatographic behaviour of diastereomers : II. Thin-Layer chromatographic behaviour of diastereomeric 1,2-disubstituted 1,2-diarylethanes

作者: M.D. Palamareva , B.J. Kurtev

DOI: 10.1016/S0021-9673(00)93771-3

关键词: Solvent effectsDiastereomeric recrystallizationChromatographyDiastereomerQualitative analysisSolvent systemSilica gelThin layer chromatographicChemistryOrganic chemistry

摘要: Abstract Another 15 pairs of diastereomeric 1,2-disubstituted 1,2-diarylethanes have been separated by thin-layer chromatography on silica gel using solvent systems with and without secondary effects. The results obtained, together those from a previous study, indicate correlation RF(erythro) >RF(threo) for 50 the 52 studied. Qualitative analysis means Snyder's theory has used to specify scope limitation this diastereomers type

参考文章(18)
Mariana Palamareva, Marietta Haimova, Bogdan Kurtev, Diastereomere Isochromane auserythro- undthreo-3-Hydroxy-2,-diarylpropionsäure-methylester Chemische Berichte. ,vol. 109, pp. 274- 284 ,(1976) , 10.1002/CBER.19761090128
M.N. Preobrazhenskaya, L.N. Mikhailova, A.A. Chemerisskaya, Thin-layer chromatographic mobility of diastereoisomers Journal of Chromatography A. ,vol. 61, pp. 269- 278 ,(1971) , 10.1016/S0021-9673(00)92419-1
Günther Drefahl, Günther Heublein, Karl Silbermann, Dünnschichtchromatographische Trennung von Diastereomeren an Kieselgel-D Journal of Chromatography A. ,vol. 22, pp. 460- 464 ,(1966) , 10.1016/S0021-9673(01)97124-9
P.D. Cooper, Thin-layer chromatographic separations of some geometric isomers Journal of Chromatography A. ,vol. 67, pp. 184- 185 ,(1972) , 10.1016/S0021-9673(01)97167-5
L. R. Snyder, Role of the solvent in liquid-solid chromatography. Review Analytical Chemistry. ,vol. 46, pp. 1384- 1393 ,(1974) , 10.1021/AC60347A052
Patrick Hubert, Edith Dellacherie, Thin-layer chromatographic separation of dipeptide and tripeptide diastereo-isomers Journal of Chromatography A. ,vol. 80, pp. 144- 145 ,(1973) , 10.1016/S0021-9673(01)85362-0